Sandia National Laboratories

About: Sandia National Laboratories is a facility organization based out in Livermore, California, United States. It is known for research contribution in the topics: Laser & Thin film. The organization has 21501 authors who have published 46724 publications receiving 1484388 citations. The organization is also known as: SNL & Sandia National Labs.

In situ transmission electron microscopy study of electrochemical sodiation and potassiation of carbon nanofibers.

Abstract: Carbonaceous materials have great potential for applications as anodes of alkali-metal ion batteries, such as Na-ion batteries and K-ion batteries (NIB and KIBs). We conduct an in situ study of the electrochemically driven sodiation and potassiation of individual carbon nanofibers (CNFs) by transmission electron microscopy (TEM). The CNFs are hollow and consist of a bilayer wall with an outer layer of disordered-carbon (d-C) enclosing an inner layer of crystalline-carbon (c-C). The d-C exhibits about three times volume expansion of the c-C after full sodiation or potassiation, thus suggesting a much higher storage capacity of Na or K ions in d-C than c-C. For the bilayer CNF-based electrode, a steady sodium capacity of 245 mAh/g is measured with a Coulombic efficiency approaching 98% after a few initial cycles. The in situ TEM experiments also reveal the mechanical degradation of CNFs through formation of longitudinal cracks near the c-C/d-C interface during sodiation and potassiation. Geometrical changes...

Natural convection in an enclosed vertical air layer with large horizontal temperature differences

Abstract: Steady-state two-dimensional results obtained from numerical solutions to the transient Navier-Stokes equations are given for laminar convective motion of a gas in an enclosed vertical slot with large horizontal temperature differences. We present results for air using the ideal-gas law and Sutherland-law transport properties, although the results are also valid for hydrogen. Wide ranges of aspect-ratio, Rayleigh-number and temperature-difference parameters are examined. The results are compared in detail with the exact solution in the conduction and fully developed merged boundary-layer limits for arbitrary temperature difference, and to the well-established Boussinesq limit for small temperature difference. It is found that the static pressure, and temperature and velocity distributions are very sensitive to property variations, even though the average heat flux is not. In addition we observe a net vertical heat flux to be the same as that obtained from the Boussinesq equations. We concentrate on the boundary-layer regime, but we present a rather complete picture of different flow regimes in Rayleigh-number, aspect-ratio and temperaturedifference parameter space. We observe that, with increasing temperature difference, lower critical Rayleigh numbers for stationary and oscillatory instabilities are obtained. In addition we observe that in some cases the physical nature of the instability changes with increasing temperature difference.

Spacecraft Formation Flying Control Using Mean Orbit Elements

Abstract: Two nonlinear feedback control laws are presented for reestablishing a desired J2 invariant relative orbit. Since it is convenient to describe the relative orbit of a deputy with respect to a chief satellite in terms of mean orbit element differences, and because the conditions for a relative orbit being J2 invariant are expressed in terms of mean orbit elements, the first control law feeds back errors in terms of mean orbit elements. Dealing with mean orbit elements has the advantage that short period oscillations are not perceived as tracking errors; rather, only the long term tracking errors are compensated for. The second control law feeds back traditional Cartesian position and velocity tracking errors. For both of the control laws, the desired orbit is computed using mean orbit elements. A numerical study compares and contrasts the two feedback laws.

Interpretations of Indentation Size Effects

Abstract: For very shallow indentations in W, Al, Au, and Fe-3wt%Si single crystals, hardness decreased with increasing depth irrespective of increasing or decreasing strain gradients. As such, strain gradient theory appears insufficient to explain the indentation size effect (ISE) at depths less than several hundred nanometers. Present research links the ISE to a ratio between the energy of newly created surface and plastic strain energy dissipation. Also, the contact surface to plastic volume ratio was nearly constant for a range of shallow depths. Based on the above, an analytical model of hardness versus depth provides a satisfactory fit to the experimental data and correlates well with embedded atom simulations. ©2002 ASME