University of Malaya

About: University of Malaya is a education organization based out in Kuala Lumpur, Malaysia. It is known for research contribution in the topics: Population & Fiber laser. The organization has 25087 authors who have published 51491 publications receiving 1036791 citations. The organization is also known as: UM & Universiti Malaya.

Impact of climate change on irrigation water demand of dry season Boro rice in northwest Bangladesh

Abstract: Climate change will affect irrigation water demand of rice via changes in rice physiology and phenology, soil water balances, evapotranspiration and effective precipitation. As agriculture is the main sector of water use in Bangladesh, estimation of the agricultural water demand in the changing environment is essential for long-term water resources development and planning. In the present paper, a study has been carried out to estimate the change of irrigation water demand in dry-season Boro rice field in northwest Bangladesh in the context of global climate change. The study shows that there will be no appreciable changes in total irrigation water requirement due to climate change. However, there will be an increase in daily use of water for irrigation. As groundwater is the main source of irrigation in northwest Bangladesh, higher daily pumping rate in dry season may aggravate the situation of groundwater scarcity in the region.

Catalytic thermochemical conversion of biomass for biofuel production: A comprehensive review

Abstract: The increasing demand for energy and diminishing sources of fossil fuels have called for the discovery of new energy sources. The effective energy conversion process of biomass is able to fulfill energy needs. Among the advanced biomass conversion technologies, thermochemical processes hold considerable potential approaches and needed for optimization. Thus, this study presents a comprehensive review of the research and development on the effects of catalysts on the thermochemical conversion of biomass to determine the progress of catalytic thermochemical conversion processes. The effects of catalysts on torrefaction, pyrolysis, hydrothermal liquefaction, and gasification are highlighted. Aspects related to reaction conditions, reactor types, and products are discussed comprehensively with the reaction mechanisms involved in the catalytic effects. Hydrogenation and hydrodeoxygenation can occur in the presence of zeolite catalysts during fast pyrolysis while producing highly aromatic bio-oil. A heterogeneous catalyst in liquefaction increases the hydrocarbon content and decreases viscosity, acid value, and oxygenated compounds in the bio-oil. Thus, expanding and enhancing knowledge about catalyst utilization in the thermochemical conversion technologies of biomass will play an important role in the generation of renewable and carbon-neutral fuels.

Heat transfer and fluid flow characteristics in microchannels heat exchanger using nanofluids: A review

Abstract: Advancement in the electronics industry led to the development of microscale heat transfer devices which offered high heat transfer coefficient in a compact size. Nevertheless, the heat transfer characteristics were limited by the heat transfer fluids that were used. The recent development of nanotechnology led to the concept of using suspended nanoparticles in heat transfer fluids to improve the heat transfer coefficient of the base fluids. The amount of research done in this particular field is fairly new and limited. Most studies done on microchannel devices and nanofluids recently have reported enhanced heat transfer capabilities and results that challenge traditional theories and limitations on heat transfer devices and fluids. Several important aspects of microchannel heat exchangers that affect the performance such as channel geometry, fluid inlet and outlet arrangement, type of construction were discussed together with the reported findings from experimental, numerical and theoretical literatures. This review also focuses on the important aspects of nanofluids such as types, properties and heat transfer characteristics and limitations towards the application of nanofluids. Apart from that, a comprehensive review on the work done regarding to heat transfer and fluid flow characteristics in microchannels heat exchanger using conventional fluids as well as nanofluids is also described.

Clathration of Two-Dimensional Coordination Polymers: Synthesis and Structures of [M(4,4'-bpy)(2)(H(2)O)(2)](ClO(4))(2).(2,4'-bpy)(2).H(2)O and [Cu(4,4'-bpy)(2)(H(2)O)(2)](ClO(4))(4).(4,4'-H(2)Bpy) (M = Cd(II), Zn(II) and bpy = Bipyridine).

Abstract: In the presence of guest 2,4'-bpy molecules or under acidic conditions, three compounds, [Cd(4,4'-bpy)(2)(H(2)O)(2)](ClO(4))(2).(2,4'-bpy)(2).H(2)O (1), [Zn(4,4'-bpy)(2)(H(2)O)(2)](ClO(4))(2).(2,4'-bpy)(2).H(2)O (2), and [Cu(4,4'-bpy)(2)(H(2)O)(2)](ClO(4))(4).(4,4'-H(2)bpy) (3), were obtained from the reactions of the metal salts and 4,4'-bpy in an EtOH-H(2)O mixture. 1 has a 2-D square-grid network structure, crystallizing in the monoclinic space group P2/n, with a = 13.231(3) A, b = 11.669(2) A, c = 15.019(3) A, beta = 112.82(3) degrees, Z = 2; 2 is isomorphous with 1, crystallizing in the monoclinic space group P2/n, with a = 13.150(3) A, b = 11.368(2) A, c = 14.745(3) A, beta = 110.60(3) degrees, Z = 2. The square grids superpose on each other into a channel structure, in which each layer consists of two pairs of shared edges, perfectly square-planar with an M(II) ion and a 4,4'-bpy at each corner and side, respectively. The square cavity has dimensions of 11.669(2) x 11.788(2) and 11.368(2) x 11.488(2) A for 1 and 2, respectively. Every two guest 2,4'-bpy molecules are clathrated in each hydrophobic host cavity and are further stabilized by pi-pi stacking and hydrogen bonding interactions. The NMR spectra clearly confirm that both 1 and 2 contain 4,4'-bpy and 2,4'-bpy molecules in a 1:1 ratio, which have stacking interaction with each other in the solution. 3 crystallizes in the orthorhombic space group Ibam, with a = 11.1283(5) A, b = 15.5927(8) A, c = 22.3178(11) A, Z = 4. 3 is made up of two-dimensional square [Cu(4)(4,4'-bpy)(4)] grids, where the square cavity has dimensions of 11.13 x 11.16 A. Each [4,4'-H(2)bpy](2+) cation is clathrated in a square cavity and stacks with one pair of opposite edges of the host square cavity in an offset fashion with the face-to-face distance of ca. 3.95 A. Within each cavity, the [4,4'-H(2)bpy](2+) cation forms twin three-center hydrogen bonds with two pairs of ClO(4)(-) anions. The results suggest that the guest 2,4'-bpy molecules and protonated [4,4'-H(2)bpy](2+) cations present in the reaction systems serve as structure-directing templates in the formation of the crystal structures and exclude self-inclusion of the networks having larger square cavities.