Journal ArticleDOI
Application of commercial microwave ovens to organic synthesis.
Reads0
Chats0
TLDR
In this article, commercial microwave ovens have been safely used to dramatically reduce the reaction times (at comparable yield) of Diels-Alder, Claisen, and ene reactions.About:
This article is published in Tetrahedron Letters.The article was published on 1986-01-01. It has received 1028 citations till now. The article focuses on the topics: Microwave oven.read more
Citations
More filters
Journal ArticleDOI
Highly-selective and high-speed Claisen rearrangement induced with subcritical water microreaction in the absence of catalyst
Masahiro Sato,Nobuhiro Otabe,Tomoya Tuji,Keiichiro Matsushima,Hajime Kawanami,Maya Chatterjee,Toshiro Yokoyama,Yutaka Ikushima,Toshishige Maro Suzuki +8 more
TL;DR: Highly-selective, high-speed aromatic and aliphatic Claisen rearrangement was shown to give the corresponding product in an excellent yield induced by subcritical water microreaction in the absence of catalyst.
Journal ArticleDOI
Efficient nucleophilic substitution reactions of quinolyl and isoquinolyl halides with nucleophiles under focused microwave irradiation
TL;DR: In this paper, nucleophilic substitution reactions of 2-chloroquinoline, 3-bromo-quinoline and 4bromoiso-quinoline with thiolate, alkoxy ions and aniline were completed within several minutes under microwave irradiation.
Journal ArticleDOI
Microwave sintering of nickel ferrite nanoparticles processed via sol–gel method
M. Penchal Reddy,M. Penchal Reddy,W. Madhuri,K. Sadhana,Il Gon Kim,K. N. Hui,K. S. Hui,K. V. Siva Kumar,R. Ramakrishna Reddy +8 more
TL;DR: In this paper, the NiFe2O4 powder was calcined in the 2.45 GHz singlemode microwave furnace to synthesize nickel nanopowder, which has the advantage of reducing the total processing time and the soak temperature.
Journal ArticleDOI
Supercapacitor electrode fabrication through chemical and physical routes
TL;DR: In this paper , the performance of supercapacitors is highly dependent on the synthesis route used for electrode materials preparation, such as vacuum filtration and mechanochemical methods, and the scalability to develop flexible structures is an attractive feature of physical approaches.
Journal ArticleDOI
Tandem Claisen Rearrangement/6-endo Cyclization Approach to Allylated and Prenylated Chromones
TL;DR: Allyl, dimethylallyl and prenyl ethers derived from o-acylphenols reacted upon microwave irradiation to form C-allylated or -prenylated chromone derivatives, depending on the substitution pattern of the arene and the allyl substituent, which is potentially useful for the synthesis of natural products and drugs.
References
More filters
Journal ArticleDOI
Acceleration of the diels-alder reaction by aluminum chloride
Peter Yates,Philip E. Eaton +1 more
Journal ArticleDOI
Some Reactions of Δ2-Cyclohexenone, Including the Synthesis of Bicyclo(2,2,2)-octanedione-2,6
Journal ArticleDOI
The reaction of anthracene with maleic and fumaric acid and their derivatives and with citraconic anhydride and mesaconic acid.
W. E. Bachmann,L. B. Scott +1 more
TL;DR: The initial precipitate of long dense needles had become contaminated by a small superficial layer of fluffy crystalline balls, apparently containing the saturated dioltrione (XXIV) and after two further recrystallizations from alcohol melted at 23!-238’.
Journal ArticleDOI
Chlorination of organoboranes: synthesis of (z)-vinyl chlorides
TL;DR: Chloration d'(alcene-1yl dihydroxy) boranes et obtention stereoselective de cis-chloro-1 alcenes as mentioned in this paper.