Journal ArticleDOI
Application of commercial microwave ovens to organic synthesis.
TLDR
In this article, commercial microwave ovens have been safely used to dramatically reduce the reaction times (at comparable yield) of Diels-Alder, Claisen, and ene reactions.About:
This article is published in Tetrahedron Letters.The article was published on 1986-01-01. It has received 1028 citations till now. The article focuses on the topics: Microwave oven.read more
Citations
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Application of microwave dielectric loss heating effects for the rapid and convenient synthesis of coordination compounds
TL;DR: A wide range of coordination compounds of substitutionally-inert transition metal ions have been rapidly and conveniently synthesized using microwave dielectric loss heating effects as discussed by the authors, which can sustain temperatures up to 250°C and pressures up to 80 atm.
Journal ArticleDOI
Enhanced persulfate oxidation of organic pollutants and removal of total organic carbons using natural magnetite and microwave irradiation
Limin Hu,Peng Wang,Guangshan Zhang,Guangshan Zhang,Guoshuai Liu,Yang Li,Tianyao Shen,John C. Crittenden +7 more
TL;DR: In this article, natural magnetite and microwave irradiation were applied to activate persulfate (PS) for the degradation of p-nitrophenol (PNP) with superior activity.
Journal ArticleDOI
New Synthetic Method of Aromatic Ethers Under Microwave Irradiation in Dry Media
TL;DR: Under microwave irradiation, phenols react remarkably fast with a number of primary alkyl halides to give aromatic ethers as mentioned in this paper, which is a very interesting property of phenols.
Journal ArticleDOI
First synthesis of N-(3-carboxylpropyl)-5-amino-2-hydroxy-3- tridecyl-1,4-benzoquinone, an unusual quinone isolated from Embelia ribes.
TL;DR: The key steps are a microwave-assisted combined Mitsunobu reaction-Claisen rearrangement to introduce the alkyl side chain into 2,5-dimethoxyphenol, followed by alkene reduction, oxidation to the quinone, and sequential displacement of the methoxy groups with hydroxide and GABA tert-butyl ester.
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Kinetic study of meso‐tetraphenylporphyrin synthesis under microwave irradiation
Rodrigo De Paula,Maria A. F. Faustino,Diana C. G. A. Pinto,Maria G. P. M. S. Neves,José A. S. Cavaleiro +4 more
TL;DR: In this paper, a typical synthesis of meso-tetraphenylporphyrin was carried out from condensation of pyrrole with benzaldehyde in acidic medium under microwave irradiation.
References
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Journal ArticleDOI
Acceleration of the diels-alder reaction by aluminum chloride
Peter Yates,Philip E. Eaton +1 more
Journal ArticleDOI
Some Reactions of Δ2-Cyclohexenone, Including the Synthesis of Bicyclo(2,2,2)-octanedione-2,6
Journal ArticleDOI
The reaction of anthracene with maleic and fumaric acid and their derivatives and with citraconic anhydride and mesaconic acid.
W. E. Bachmann,L. B. Scott +1 more
TL;DR: The initial precipitate of long dense needles had become contaminated by a small superficial layer of fluffy crystalline balls, apparently containing the saturated dioltrione (XXIV) and after two further recrystallizations from alcohol melted at 23!-238’.
Journal ArticleDOI
Chlorination of organoboranes: synthesis of (z)-vinyl chlorides
TL;DR: Chloration d'(alcene-1yl dihydroxy) boranes et obtention stereoselective de cis-chloro-1 alcenes as mentioned in this paper.