Journal ArticleDOI
Application of commercial microwave ovens to organic synthesis.
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In this article, commercial microwave ovens have been safely used to dramatically reduce the reaction times (at comparable yield) of Diels-Alder, Claisen, and ene reactions.About:
This article is published in Tetrahedron Letters.The article was published on 1986-01-01. It has received 1028 citations till now. The article focuses on the topics: Microwave oven.read more
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Investigation of Selective Microwave Heating Phenomena in the Reactions of 2-Substituted Pyridines*
Péter Bana,István Greiner +1 more
TL;DR: In this paper, the authors investigated selective microwave heating effects in a rearrangement and a benzylation reaction involving 2-substituted pyridines using both external infrared and internal fibre optic sensors.
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Search for the Microwave Nonthermal Effect in Microwave Chemistry: Synthesis of the Heptyl Butanoate Ester with Microwave Selective Heating of a Sulfonated Activated Carbon Catalyst
TL;DR: In this paper, a heptyl butanoate ester was synthesized from butanoic acid and heptanol in a heterogeneous medium in the presence of sulfonated activated carbon (AC-SO3H) catalyst particles subjected to microwave irradiation, which led to higher conversion yields than conventional heating with an oil bath.
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Quantum Tunneling Contribution for the Activation Energy in Microwave-Induced Reactions
TL;DR: The results indicate the need to move toward the use of more refined methods of modern quantum chemistry to calculate more accurately field-induced reaction rates and effective activation energies.
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Application of microwave radiation in petrochemical processes
TL;DR: In this article, the influence of a 2450-MHz microwave radiation on the synthesis of cyclic acetals and heterocyclic compounds and product yields is shown and results of research on the development of new technologies and reactors with microwave heating for petrochemical industry are summarized.
References
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Journal ArticleDOI
Acceleration of the diels-alder reaction by aluminum chloride
Peter Yates,Philip E. Eaton +1 more
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Some Reactions of Δ2-Cyclohexenone, Including the Synthesis of Bicyclo(2,2,2)-octanedione-2,6
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The reaction of anthracene with maleic and fumaric acid and their derivatives and with citraconic anhydride and mesaconic acid.
W. E. Bachmann,L. B. Scott +1 more
TL;DR: The initial precipitate of long dense needles had become contaminated by a small superficial layer of fluffy crystalline balls, apparently containing the saturated dioltrione (XXIV) and after two further recrystallizations from alcohol melted at 23!-238’.
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Chlorination of organoboranes: synthesis of (z)-vinyl chlorides
TL;DR: Chloration d'(alcene-1yl dihydroxy) boranes et obtention stereoselective de cis-chloro-1 alcenes as mentioned in this paper.