Aalto University

About: Aalto University is a education organization based out in Espoo, Finland. It is known for research contribution in the topics: Computer science & Context (language use). The organization has 9969 authors who have published 32648 publications receiving 829626 citations. The organization is also known as: TKK & Aalto-korkeakoulu.

Azobenzene photomechanics: prospects and potential applications

Abstract: The change in shape inducible in some photo-reversible molecules using light can effect powerful changes to a variety of properties of a host material. This class of reversible light-switchable molecules includes molecules that photo-dimerize, such as coumarins and anthracenes; those that allow intra-molecular photo-induced bond formation, such as fulgides, spiro-pyrans, and diarylethenes; and those that exhibit photo-isomerization, such as stilbenes, crowded alkenes, and azobenzenes. The most ubiquitous natural molecule for reversible shape change, however, and perhaps the inspiration for all artificial bio-mimics, is the rhodopsin/retinal protein system that enables vision, and this is the quintessential reversible photo-switch for performance and robustness. Here, the small retinal molecule embedded in a cage of rhodopsin helices isomerizes from a cis geometry to a trans geometry around a C=C double bond with the absorption of just a single photon. The modest shape change of just a few angstroms is quickly amplified and sets off a cascade of larger shape and chemical changes, eventually culminating in an electrical signal to the brain of a vision event, the energy of the input photon amplified many thousands of times in the process. Complicated biochemical pathways then revert the trans isomer back to cis, and set the system back up for another cascade upon subsequent absorption. The reversibility is complete, and many subsequent cycles are possible. The reversion mechanism back to the initial cis state is complex and enzymatic, hence direct application of the retinal/rhodopsin photo-switch to engineering systems is difficult. Perhaps the best artificial mimic of this strong photo-switching effect however in terms of reversibility, speed, and simplicity of incorporation, is azobenzene. Trans and cis states can be switched in microseconds with low-power light, reversibility of 105 and 106 cycles is routine before chemical fatigue, and a wide variety of molecular architectures is available to the synthetic materials chemist, permitting facile anchoring and compatibility, as well as chemical and physical amplification of the simple geometric change. This review article focuses on photo-mechanical effect taking place in various material systems incorporating azobenzene. The photo-mechanical effect can be defined as reversible change in shape by absorption of light, which results in a significant macroscopic mechanical deformation, and reversible mechanical actuation, of the host material. Thus, we exclude simple thermal expansion effects, reversible but non-mechanical photo-switching or photo-chemistry, as well as the wide range of optical and electro-optical switching effects for which good reviews exist elsewhere. Azobenzene-based material systems are also of great interest for light energy harvesting applications across much of the solar spectrum, yet this emerging field is still in an early enough stage of research output as to not yet warrant review, but we hope that some of the ideas put forward here toward promising future directions of research, will help guide the field.

Hanbury-Brown and Twiss exchange and non-equilibrium-induced correlations in disordered, four-terminal graphene-ribbon conductor.

Abstract: We have investigated current-current correlations in a cross-shaped conductor made of graphene. The mean free path of charge carriers is on the order of the ribbon width which leads to a hybrid conductor where there is diffusive transport in the device arms while the central connection region displays near ballistic transport. Our data on auto and cross correlations deviate from the predictions of Landauer-Buttiker theory, and agreement can be obtained only by taking into account contributions from non-thermal electron distributions at the inlets to the semiballistic center, in which the partition noise becomes strongly modified. The experimental results display distinct Hanbury – Brown and Twiss (HBT) exchange correlations, the strength of which is boosted by the non-equilibrium occupation-number fluctuations internal to this hybrid conductor. Our work demonstrates that variation in electron coherence along atomically-thin, two-dimensional conductors has significant implications on their noise and cross correlation properties.

Effect of microfibrillated cellulose and fines on the drainage of kraft pulp suspension and paper strength

Abstract: Different types of microfibrillated cellulose (MFC) and fines suspensions were produced, characterized, and then added to a papermaking pulp suspension. High and medium molar mass cationic polyelectrolytes were used as fixatives. The drainage behavior of the pulp suspensions with additives were evaluated against the strength properties of hand sheets made thereof. The effects of salt concentration, pH, fixative type, dosage and type of fibrillar material on drainage were examined. All the MFC and fines samples produced had clearly different properties due to their dissimilar production methods, and they also introduced specific responses on the measured drainage and paper strength. Generally, the addition of MFC decreased the drainage rate of pulp suspension and increased the strength of paper. However, it was shown that by optimum selection of materials and process conditions an enhancement of the strength properties could be achieved without simultaneously deteriorating the drainage.

Planck 2013 results. XXV. Searches for cosmic strings and other topological defects

Abstract: Planck data have been used to provide stringent new constraints on cosmic strings and other defects. We describe forecasts of the CMB power spectrum induced by cosmic strings, calculating these from network models and simulations using line-of-sight Boltzmann solvers. We have studied Nambu-Goto cosmic strings, as well as field theory strings for which radiative effects are important, thus spanning the range of theoretical uncertainty in strings models. We have added the angular power spectrum from strings to that for a simple adiabatic model, with the extra fraction defined as $f_{10}$ at multipole $\ell=10$. This parameter has been added to the standard six parameter fit using COSMOMC with flat priors. For the Nambu-Goto string model, we have obtained a constraint on the string tension of $G\mu/c^2 < 1.5 x 10^{-7}$ and $f_{10} < 0.015$ at 95% confidence that can be improved to $G\mu/c^2 < 1.3 x 10^{-7}$ and $f_{10} < 0.010$ on inclusion of high-$\ell$ CMB data. For the abelian-Higgs field theory model we find, $G\mu_{AH}/c^2 < 3.2 x 10^{-7}$ and $f_{10} < 0.028$. The marginalized likelihoods for $f_{10}$ and in the $f_{10}$--$\Omega_b h^2$ plane are also presented. We have also obtained constraints on $f_{10}$ for models with semi-local strings and global textures for which $G\mu/c^2 < 1.1 x 10^{-6}$. We have made complementarity searches for the specific non-Gaussian signatures of cosmic strings, calibrating with all-sky Planck resolution CMB maps generated from networks of post-recombination strings. We have obtained upper limits on the string tension at 95% confidence of $G\mu/c^2 < 8.8 x 10^{-7}$ using modal bispectrum estimation and $G\mu/c^2 < 7.8 x 10^{-7}$ for real space searches with Minkowski functionals. These are conservative upper bounds because only post-recombination string contributions have been included in the non-Gaussian analysis.