Aalto University

About: Aalto University is a education organization based out in Espoo, Finland. It is known for research contribution in the topics: Computer science & Context (language use). The organization has 9969 authors who have published 32648 publications receiving 829626 citations. The organization is also known as: TKK & Aalto-korkeakoulu.

Single-Shell Carbon-Encapsulated Iron Nanoparticles: Synthesis and High Electrocatalytic Activity for Hydrogen Evolution Reaction

Abstract: Efficient hydrogen evolution reaction (HER) through effective and inexpensive electrocatalysts is a valuable approach for clean and renewable energy systems. Here, single-shell carbon-encapsulated iron nanoparticles (SCEINs) decorated on single-walled carbon nanotubes (SWNTs) are introduced as a novel highly active and durable non-noble-metal catalyst for the HER. This catalyst exhibits catalytic properties superior to previously studied nonprecious materials and comparable to those of platinum. The SCEIN/SWNT is synthesized by a novel fast and low-cost aerosol chemical vapor deposition method in a one-step synthesis. In SCEINs the single carbon layer does not prevent desired access of the reactants to the vicinity of the iron nanoparticles but protects the active metallic core from oxidation. This finding opens new avenues for utilizing active transition metals such as iron in a wide range of applications.

On mm-Wave Multipath Clustering and Channel Modeling

Abstract: Efficient and realistic mm-wave channel models are of vital importance for the development of novel mm-wave wireless technologies. Though many of the current 60 GHz channel models are based on the useful concept of multipath clusters, only a limited number of 60 GHz channel measurements have been reported in the literature for this purpose. Therefore, there is still a need for further measurement based analyses of multipath clustering in the 60 GHz band. This paper presents clustering results for a double-directional 60 GHz MIMO channel model. Based on these results, we derive a model which is validated with measured data. Statistical cluster parameters are evaluated and compared with existing channel models. It is shown that the cluster angular characteristics are closely related to the room geometry and environment, making it infeasible to model the delay and angular domains independently. We also show that when using ray tracing to model the channel, it is insufficient to only consider walls, ceiling, floor and tables; finer structures such as ceiling lamps, chairs and bookshelves need to be taken into account as well.

Angular momenta and spin-orbit interaction of nonparaxial light in free space

Abstract: We give an exact self-consistent operator description of the spin and orbital angular momenta, position, and spin-orbit interactions of nonparaxial light in free space. Both quantum-operator formalism and classical energy-flow approach are presented. We apply the general theory to symmetric and asymmetric Bessel beams exhibiting spin- and orbital-dependent intensity profiles. The exact wave solutions are clearly interpreted in terms of the Berry phases, quantization of caustics, and Hall effects of light, which can be readily observedexperimentally.

Polarization and Thickness Dependent Absorption Properties of Black Phosphorus: New Saturable Absorber for Ultrafast Pulse Generation.

Abstract: Black phosphorus (BP) has recently been rediscovered as a new and interesting two-dimensional material due to its unique electronic and optical properties. Here, we study the linear and nonlinear optical properties of BP flakes. We observe that both the linear and nonlinear optical properties are anisotropic and can be tuned by the film thickness in BP, completely different from other typical two-dimensional layered materials (e.g., graphene and the most studied transition metal dichalcogenides). We then use the nonlinear optical properties of BP for ultrafast (pulse duration down to ~786 fs in mode-locking) and large-energy (pulse energy up to >18 nJ in Q-switching) pulse generation in fiber lasers at the near-infrared telecommunication band ~1.5 μm. We observe that the output of our BP based pulsed lasers is linearly polarized (with a degree-of-polarization ~98% in mode-locking, >99% in Q-switching, respectively) due to the anisotropic optical property of BP. Our results underscore the relatively large optical nonlinearity of BP with unique polarization and thickness dependence, and its potential for polarized optical pulse generation, paving the way to BP based nonlinear and ultrafast photonic applications (e.g., ultrafast all-optical polarization switches/modulators, frequency converters etc.).