University of Massachusetts Amherst

About: University of Massachusetts Amherst is a education organization based out in Amherst Center, Massachusetts, United States. It is known for research contribution in the topics: Population & Galaxy. The organization has 37274 authors who have published 83965 publications receiving 3834996 citations. The organization is also known as: UMass Amherst & Massachusetts State College.

Lipid Oxidation in Oil-in-Water Emulsions: Impact of Molecular Environment on Chemical Reactions in Heterogeneous Food Systems

Abstract: The susceptibility of lipids to oxidation is a major cause of quality deterioration in food emulsions. The reaction mechanism and factors that influence oxidation are appreciably different for emulsified lipids than for bulk lipids. This article reviews the current understanding of the lipid oxidation mechanism in oil-in-water emulsions. It also discusses the major factors that influence the rate of lipid oxidation in emulsions, such as antioxidants, chelating agents, ingredient purity, ingredient partitioning, interfacial characteristics, droplet characteristics, and ingredient interactions. This knowledge is then used to define effective strategies for controlling lipid oxidation in food emulsions.

Energy consumption in mobile phones: a measurement study and implications for network applications

Abstract: In this paper, we present a measurement study of the energy consumption characteristics of three widespread mobile networking technologies: 3G, GSM, and WiFi. We find that 3G and GSM incur a high tail energy overhead because of lingering in high power states after completing a transfer. Based on these measurements, we develop a model for the energy consumed by network activity for each technology.Using this model, we develop TailEnder, a protocol that reduces energy consumption of common mobile applications. For applications that can tolerate a small delay such as e-mail, TailEnder schedules transfers so as to minimize the cumulative energy consumed meeting user-specified deadlines. We show that the TailEnder scheduling algorithm is within a factor 2x of the optimal and show that any online algorithm can at best be within a factor 1.62x of the optimal. For applications like web search that can benefit from prefetching, TailEnder aggressively prefetches several times more data and improves user-specified response times while consuming less energy. We evaluate the benefits of TailEnder for three different case study applications - email, news feeds, and web search - based on real user logs and show significant reduction in energy consumption in each case. Experiments conducted on the mobile phone show that TailEnder can download 60% more news feed updates and download search results for more than 50% of web queries, compared to using the default policy.

GOODS–Herschel: an infrared main sequence for star-forming galaxies

Abstract: We present the deepest 100 to 500 μm far-infrared observations obtained with the Herschel Space Observatory as part of the GOODS-Herschel key program, and examine the infrared (IR) 3–500 μm spectral energy distributions (SEDs) of galaxies at 0 < z < 2.5, supplemented by a local reference sample from IRAS, ISO, Spitzer, and AKARI data. We determine the projected star formation densities of local galaxies from their radio and mid-IR continuum sizes. We find that the ratio of total IR luminosity to rest-frame 8 μm luminosity, IR8 (≡ L_(IR)^(tot)/L_8), follows a Gaussian distribution centered on IR8 = 4 (σ = 1.6) and defines an IR main sequence for star-forming galaxies independent of redshift and luminosity. Outliers from this main sequence produce a tail skewed toward higher values of IR8. This minority population ( 3 × 10^(10) L_⊙ kpc^(-2)) and a high specific star formation rate (i.e., starbursts). The rest-frame, UV-2700 A size of these distant starbursts is typically half that of main sequence galaxies, supporting the correlation between star formation density and starburst activity that is measured for the local sample. Locally, luminous and ultraluminous IR galaxies, (U)LIRGs (L_(IR)^(tot)≥ 10^(11) L_☉), are systematically in the starburst mode, whereas most distant (U)LIRGs form stars in the “normal” main sequence mode. This confusion between two modes of star formation is the cause of the so-called “mid-IR excess” population of galaxies found at z > 1.5 by previous studies. Main sequence galaxies have strong polycyclic aromatic hydrocarbon (PAH) emission line features, a broad far-IR bump resulting from a combination of dust temperatures (T_(dust) ~ 15–50 K), and an effective T_(dust) ~ 31 K, as derived from the peak wavelength of their infrared SED. Galaxies in the starburst regime instead exhibit weak PAH equivalent widths and a sharper far-IR bump with an effective T_(dust)~ 40 K. Finally, we present evidence that the mid-to-far IR emission of X-ray active galactic nuclei (AGN) is predominantly produced by star formation and that candidate dusty AGNs with a power-law emission in the mid-IR systematically occur in compact, dusty starbursts. After correcting for the effect of starbursts on IR8, we identify new candidates for extremely obscured AGNs.

Food-grade nanoemulsions: formulation, fabrication, properties, performance, biological fate, and potential toxicity.

Abstract: Nanoemulsions fabricated from food-grade ingredients are being increasingly utilized in the food industry to encapsulate, protect, and deliver lipophilic functional components, such as biologically-active lipids (e.g., ω-3 fatty acids, conjugated linoleic acid) and oil-soluble flavors, vitamins, preservatives, and nutraceuticals. The small size of the particles in nanoemulsions (r<100 nm) means that they have a number of potential advantages over conventional emulsions-higher stability to droplet aggregation and gravitational separation, high optical clarity, ability to modulate product texture, and, increased bioavailability of lipophilic components. On the other hand, there may also be some risks associated with the oral ingestion of nanoemulsions, such as their ability to change the biological fate of bioactive components within the gastrointestinal tract and the potential toxicity of some of the components used in their fabrication. This review article provides an overview of the current status of nanoemulsion formulation, fabrication, properties, applications, biological fate, and potential toxicity with emphasis on systems suitable for utilization within the food and beverage industry.

Dissimilatory Fe(III) and Mn(IV) reduction.

Abstract: Dissimilatory Fe(III) and Mn(IV) reduction has an important influence on the geochemistry of modern environments, and Fe(III)-reducing microorganisms, most notably those in the Geobacteraceae family, can play an important role in the bioremediation of subsurface environments contaminated with organic or metal contaminants. Microorganisms with the capacity to conserve energy from Fe(III) and Mn(IV) reduction are phylogenetically dispersed throughout the Bacteria and Archaea. The ability to oxidize hydrogen with the reduction of Fe(III) is a highly conserved characteristic of hyperthermophilic microorganisms and one Fe(III)-reducing Archaea grows at the highest temperature yet recorded for any organism. Fe(III)- and Mn(IV)-reducing microorganisms have the ability to oxidize a wide variety of organic compounds, often completely to carbon dioxide. Typical alternative electron acceptors for Fe(III) reducers include oxygen, nitrate, U(VI) and electrodes. Unlike other commonly considered electron acceptors, Fe(III) and Mn(IV) oxides, the most prevalent form of Fe(III) and Mn(IV) in most environments, are insoluble. Thus, Fe(III)- and Mn(IV)-reducing microorganisms face the dilemma of how to transfer electrons derived from central metabolism onto an insoluble, extracellular electron acceptor. Although microbiological and geochemical evidence suggests that Fe(III) reduction may have been the first form of microbial respiration, the capacity for Fe(III) reduction appears to have evolved several times as phylogenetically distinct Fe(III) reducers have different mechanisms for Fe(III) reduction. Geobacter species, which are representative of the family of Fe(III) reducers that predominate in a wide diversity of sedimentary environments, require direct contact with Fe(III) oxides in order to reduce them. In contrast, Shewanella and Geothrix species produce chelators that solubilize Fe(III) and release electron-shuttling compounds that transfer electrons from the cell surface to the surface of Fe(III) oxides not in direct contact with the cells. Electron transfer from the inner membrane to the outer membrane in Geobacter and Shewanella species appears to involve an electron transport chain of inner-membrane, periplasmic, and outer-membrane c-type cytochromes, but the cytochromes involved in these processes in the two organisms are different. In addition, Geobacter species specifically express flagella and pili during growth on Fe(III) and Mn(IV) oxides and are chemotactic to Fe(II) and Mn(II), which may lead Geobacter species to the oxides under anoxic conditions. The physiological characteristics of Geobacter species appear to explain why they have consistently been found to be the predominant Fe(III)- and Mn(IV)-reducing microorganisms in a variety of sedimentary environments. In comparison with other respiratory processes, the study of Fe(III) and Mn(IV) reduction is in its infancy, but genome-enabled approaches are rapidly advancing our understanding of this environmentally significant physiology.