Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage

TL;DR: The use of first row transition metal complexes is one of the mainstreams in modern homogeneous catalysis as discussed by the authors and the case of manganese is peculiar in that catalytic applications of its coordination compounds featuring nitrogen-and oxygen-based ligands are well established, whereas those of its organometallic complexes exhibiting Mn C and/or Mn H bonds are still underdeveloped and have only recently focused substantial attention.

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Immobilization of metalloporphyrins in electropolymerized films: design and applications

Fethi Bedioui, +2 more

- 01 Jan 1995 -

Accounts of Chemical Research

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Unusual Kinetic Stability of a Ground-State Singlet Oxomanganese(V) Porphyrin. Evidence for a Spin State Crossing Effect

Ning Jin, +1 more

- 11 Mar 1999 -

Journal of the American Chemical Society

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Iron-catalyzed/mediated oxidative transformation of C–H bonds

Fan Jia, +1 more

- 04 Mar 2014 -

Organic chemistry frontiers

TL;DR: In this paper, the authors focus on C-H bond cleavage in oxidative transformation via iron catalysis, as well as applications in synthetic chemistry, and present a review of the state of the art at the frontiers of chemistry.

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