Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Catalytic and asymmetric epoxidation of unfunctionalized alkenes with hydrogen peroxide and (Salen)Mn(III) complexes
TL;DR: In this paper, achiral and chiral (Salen)Mn(III) complexes with a nitrogen heterocycle as axial ligand in the presence of 30 % aqueous hydrogen peroxide as oxidant were used for catalytic epoxidation of 1,2-dihydronaphthalene and trans-β-methylstyrene.
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Synthesis, Structure, and H2O2-Dependent Catalytic Functions of Disulfide-Bridged Dicopper(I) and Related Thioether−Copper(I) and Thioether−Copper(II) Complexes
Takehiro Ohta,Takashi Tachiyama,Kazunari Yoshizawa,Tokio Yamabe,Takeshi Uchida,Teizo Kitagawa +5 more
TL;DR: Fragment molecular orbital (FMO) analyses and molecular orbital overlap population (MOOP) analyses clarify the preferable formation of the disulfide S-S bond in 1 rather than the formation of a thiolate-copper(II) complex within the Py2S- ligand framework.
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Manganese porphyrins covalently bound to silica and montmorillonite K10 as efficient catalysts for alkene and alkane oxidation by hydrogen peroxide
TL;DR: In this paper, the meso-tetrakis porphyrin derivatives bearing NH 2 or SO 3 H functions on their mesoaryl rings were covalent bound to either silica or montmorillonite K10, and these supported metalloporphyrins efficiently catalysed the epoxidation of alkenes with PhIO.
Journal ArticleDOI
Synthetische Aspekte metallkatalysierter Oxidationen von Aminen und verwandte Reaktionen
Journal ArticleDOI
Efficient and selective peracetic Acid epoxidation catalyzed by a robust manganese catalyst.
TL;DR: A manganese catalyst containing a tetradentate ligand derived from triazacyclononane exhibits high catalytic activity in epoxidation reactions using peracetic acid as oxidant and is remarkably selective toward aliphatic cis-olefins.