Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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The structure of a one-electron oxidized Mn(III)-bis(phenolate)dipyrrin radical complex and oxidation catalysis control via ligand-centered redox activity
Laureline Lecarme,Linus Chiang,Jules Moutet,Nicolas Leconte,Christian Philouze,Olivier Jarjayes,Tim Storr,Fabrice Thomas +7 more
TL;DR: This work examined the ability of complex 1+ SbF6- to catalyze the isomerization of styrene oxide and found that it is an efficient catalyst for the anti-Markovnikov opening of Styrene oxide.
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Synthesis, Characterization, and Binding of [Cr(naphen)(H2O)2]+ with DNA: Experimental and Modeling Study
TL;DR: A chromium(III) complex of naphen, where naphen denotes 1,2-bis(naphthylideneamino)ethane having the basic salen structure, with an extended aromatic system, has been synthesized and characterized using UV-visible, infrared and ESI mass spectra.
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Aerial oxidation of p-isopropyltoluene over manganese containing mesoporous MCM-41 and Al-MCM-41 molecular sieves
S. Vetrivel,Arumugam Pandurangan +1 more
TL;DR: The catalytic activity of MCM-41 after impregnation with manganese species was investigated in this paper, where the presence of Mn2+ was evident through DR UV-vis and ESR spectroscopy.
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Mimic models of peroxidase: kinetic studies of the catalytic oxidation of hydroquinone by H2O2
TL;DR: The reactions of hydroquinone with hydrogen peroxide catalyzed by transition metal ions Cu2+, Fe2+ Fe3+, Co2+ and Mn2+ were investigated and metallomicelles could be treated as the mimic models of peroxidase.
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Oxidation of alkanes by tert-butyl hydroperoxide catalyzed by polynuclear manganese Schiff base complexes
TL;DR: The polynuclear manganese(III) Schiff base complexes as mentioned in this paper were employed as catalysts for oxidation of cyclohexane by tert-butyl hydroperoxide in acetonitrile solution at room temperature.