Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Cyclohexane hydroxylation by iodosylbenzene and iodobenzene diacetate catalyzed by a new β-octahalogenated Mn–porphyrin complex: The effect of meso-3-pyridyl substituents
Gilson de Freitas Silva,Dayse Carvalho da Silva,Adriano Silva Guimarães,Eliane do Nascimento,Júlio S. Rebouças,Márcio P. de Araujo,Maria Eliza Moreira Dai de Carvalho,Ynara Marina Idemori +7 more
TL;DR: In this paper, the synthesis of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(3-pyridyl)porphyrinatomanganese(II) (Mn(II,Br 8 T3PyP), a new compound, is described along with some of its electrochemical and catalytic properties.
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Selective catalytic oxidation of naphthol to 2-hydroxyl-1,4-naphthoquinone by hydrogen peroxide over metalloporphyrin catalysts
TL;DR: In this paper, the reactions of 1-naphthol and 2-nanophthol were catalytically converted into 2-hydroxyl-1,4-nphthoquinone (HNQ, lawsone) in the presence of H2O2 over metalloporphyrin catalysts.
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Biomimetic oxidation of praziquantel catalysed by metalloporphyrins
Andrea J.B. Melo,Yassuko Iamamoto,Ana Paula Jecks Maestrin,John R. Lindsay Smith,Michel David dos Santos,Norberto Peporine Lopes,Pierina Sueli Bonato +6 more
TL;DR: In this paper, an HPLC-MS/MS investigation of praziquantel (anthelmintic agent) oxidation by iodosylbenzene in an organic medium, using iron(III) tetraarylporphyrins (where aryl=phenyl, pentafluorophenyl, 2-nitrophenyl, two-trifluoromethylphenyl and mesityl) and manganese(III), tetraphenyl porphyrin as catalysts.
Journal ArticleDOI
Magnetic Polymer Nanospheres Immobilizing Metalloporphyrins. Catalysis and Reuse to Hydroxylate Cyclohexane with Molecular Oxygen
TL;DR: Magnetic polymer nanospheres immobilizing Co(II) porphyrin or Mn(III) polymorphyrin were synthesized and their catalytic activities in hydroxylating cyclohexane were comparably investigated as mentioned in this paper.
Journal ArticleDOI
Perhalogenated 2-pyridylporphyrin complexes: synthesis, self-coordinating aggregation properties, and catalytic studies
TL;DR: In this article, the authors compared four attempted demetallation methods for ZnBr8T2PyP, including a strategy based on the acid-base properties of the macrocycle, solvent-dependent kinetics of metal insertion into porphyrins and the pH-dependent solubility of the 2-pyridylporphyrin derivatives in water.