Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
About:
This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
Citations
More filters
Journal ArticleDOI
Hemoprotein Models Based on a Covalent Helix–Heme–Helix Sandwich: 2. Structural Characterization of CoIII Mimochrome I δ and δ Isomers
Gabriella D'Auria,Ornella Maglio,Flavia Nastri,Angela Lombardi,Marco Mazzeo,Giancarlo Morelli,Livio Paolillo,Carlo Pedone,Vincenzo Pavone +8 more
TL;DR: In this article, the 3D structure of the parent compound CoIII mimochrome I was characterized by UV/visible, CD, and NMR spectroscopy, coupled with conformational energy calculations.
Journal ArticleDOI
H2O2/NaHCO3-mediated enantioselective epoxidation of olefins in NTf2-based ionic liquids and under ultrasound
Gregory Chatel,Gregory Chatel,Catherine Goux-Henry,Anaïs Mirabaud,Thomas Rossi,Nathalie Kardos,Bruno Andrioletti,Micheline Draye +7 more
TL;DR: In this paper, the benign H2O2/NaHCO3 oxidative combination was used for enantioselective epoxidation of olefins using a chiral manganese porphyrin as a catalyst.
Journal ArticleDOI
Mechanistic Study of Iron(III) [Tetrakis(pentafluorophenyl)Porphyrin Triflate (F20TPP)Fe(OTf) Catalyzed Cyclooctene Epoxidation by Hydrogen Peroxide
Ned A. Stephenson,Alexis T. Bell +1 more
TL;DR: It is shown that catalytic activity of the (F20TPP)Fe+ cation can be achieved in aprotic solvent by displacing the tightly bound chloride anion with a weakly bound triflate anion and water can coordinate to the iron porphyrin cation in aProtic systems resulting in catalyst deactivation.
Journal ArticleDOI
Origin of the Oxygen Atom in C-H Bond Oxidations Catalyzed by a Water-Soluble Metalloporphyrin.
TL;DR: The monopersulfate oxidation of 4-isopropylbenzoic acid performed in H(2)(18)O and catalyzed by a water-soluble metalloporphyrin indicated that half of the oxygen atoms incorporated in 4-(1-hydroxy-1-methylethyl)benzoylacetophenone, the primary hydroxylation product, came from water.
Journal ArticleDOI
Reactivity by design--metallaoxetanes as centerpieces in reaction development.
Alexander Dauth,Jennifer A. Love +1 more
TL;DR: Preparation and Reactivity of Metallaoxetanes 2036 5.1.