Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
About:
This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
Citations
More filters
Journal ArticleDOI
Graphene- and CNTs-based carbocatalysts in persulfates activation: Material design and catalytic mechanisms
TL;DR: In this article, a critical review on the recent practical and theoretical development in graphene and carbon nanotubes (CNTs)-based materials as carbocatalysts for the activation of peroxymonosulfate (PMS) and peroxydisulfate(PDS).
Journal ArticleDOI
Active-site-accessible, porphyrinic metal-organic framework materials.
TL;DR: The synthesis of an extended family of MOFs that directly incorporate a variety of metalloporphyrins that feature large channels and readily accessible active sites and are catalytically competent for the oxidation of alkenes and alkanes is reported here.
Journal ArticleDOI
Regioselective and enantioselective epoxidation catalyzed by metalloporphyrins
TL;DR: Both the most promising biomimetic and practical catalysts have arisen from systems that can be systematically modified by convenient synthetic methodology.
Journal ArticleDOI
Dendrimer-metalloporphyrins: Synthesis and catalysis
TL;DR: In this paper, a new class of sterically hindered dendrimer-metalloporphyrins was synthesized for use as shape-selective oxidation catalysts.
Journal ArticleDOI
Bis(μ‐oxo)dimetal “Diamond” Cores in Copper and Iron Complexes Relevant to Biocatalysis
Lawrence Que,William B. Tolman +1 more
TL;DR: The understanding of biocatalysis has been enhanced significantly through the isolation and comprehensive characterization of the Cu(2)(mu-O)(2) and Fe(2](mu- O)(2), which has led to the development of new mechanistic notions about how non-heme multimetal enzymes may function in the activation of dioxygen to catalyze a diverse array of organic transformations.