Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Highly efficient and chemoselective oxidation of sulfides catalyzed by iron(III) corroles with iodobenzene diacetate
TL;DR: In this paper, a putative high-valent iron(V)-oxo species is likely generated as a short-lived active intermediate, based on Hammett correlation and mixing UV-vis spectral studies.
Journal ArticleDOI
Reactivity Studies of Iridium(III) Porphyrins with Methanol in Alkaline Media
TL;DR: In this article, the C−O bond of CH3OH at 200 °C was cleaved using σ-bond metathesis to give Ir(ttp)CH3.
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A facile photosynthesis of trans-dioxoruthenium(VI) porphyrins.
Yan Huang,Eric Vanover,Rui Zhang +2 more
TL;DR: This work has shown that photolysis of porphyrin-ruthenium(IV) dichlorate complexes with visible light results in homolytic cleavage of the O-Cl bond in the chlorates to form trans-dioxorutenium(VI) species bearing either sterically encumbered or unencumbered p Morphyrin ligands.
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Heterogeneous catalytic properties of unprecedented μ-O-[FeTCPP]2 dimers (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin): an unusual superhyperfine EPR structure.
Arkaitz Fidalgo-Marijuan,Gotzone Barandika,Begoña Bazán,Miren Karmele Urtiaga,Edurne S. Larrea,Marta Iglesias,Luis Lezama,María I. Arriortua +7 more
TL;DR: This work reports on the synthesis and characterisation of the μ-O-[FeTCPP]2·16DMF compound (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin, DMF = N,N-dimethylformamide), one of the very few examples of metalloporphyrins where structural units act as catalysts.
Journal ArticleDOI
Primary photoprocesses in cationic 5,10,15,20-meso-tetrakis(4-N-methylpyridiniumyl)porphyrin and its transition metal complexes bound with nucleic acids
TL;DR: In this paper, the photophysical properties of meso-tetrakis(4-N-methylpyridiniumyl)porphyrin (TMpyP4) and its metallocomplexes M(II) are considered with a primary emphasis placed upon intermolecular interaction of the photoexcited porphyrins with the nearest environment.