Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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The selective functionalization of saturated hydrocarbons. Part 28. The activation of benzylic methylene groups under GoAggIV and GoAggV conditions
Derek H. R. Barton,Wang Tie-Lin +1 more
TL;DR: In this article, cyclohexadienes were oxidized to give aromatic products instead of ketones and alcohols under GoAggIV and GoAggV conditions, and xanthene, fluorene and diphenylmethane were oxidised to give the corresponding xanthone and benzophenone.
Journal ArticleDOI
Hydroxylation of Aliphatic Hydrocarbons with m-Chloroperbenzoic Acid Catalyzed by Electron-Deficient Iron(III) Porphyrin Complexes.
TL;DR: In this paper, the effects of the electronic nature of iron porphyrin complexes, the concentration of H218O, the C-H bond strength of alkanes, and the reaction temperature on the 18O-incorporation from the labeled water into alcohols were investigated.
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Synthesis, characterization and catalytic activity of polynuclear manganese complexes of 2,5-dihydroxyterephthalaldehyde for epoxidation of olefins with H2O2
R. Krishnan,S. Vancheesan +1 more
TL;DR: In this paper, the effect of imidazole and olefin concentrations on effective oxygen transfer was studied under heterogenized homogeneous reaction conditions in the presence of a base.
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Carbenoide Komplexverbindungen elektronenarmer Übergangsmetalle — Synthesen von und mit kurzlebigen Synthesebausteinen
TL;DR: In this article, the Planbarkeit metallorganischer Synthesen erhoht, verbunden with dem Verstandnis des subtilen Wechselspiels zwischen Zentralmetall, Liganden and Substraten, is discussed.
Journal ArticleDOI
Comparative study of catalytic activity of some biomimetic models of cytochrome P450 in oxidation of olefins with tetra-n-butylammonium periodate: Electron-rich Mn-porphyrins versus the electron-deficient ones
TL;DR: In this article, a wide range of cyclic and acyclic olefins with tetra-nbutylammonium periodate (TNB) was used to investigate the electron-withdrawing effects of meso-and β-substituents.