Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Highly reactive electrophilic oxidants in cytochrome P450 catalysis.
TL;DR: An overview of recent studies directed at detection of the electrophilic oxidants in P450 enzymes and the accumulated evidence for two distinct species is discussed.
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Non-heme iron polyazadentate complexes as catalysts for oxidations by H2O2: particular efficiency in aromatic hydroxylations and beneficial effects of a reducing agent
Véronique Balland,Delphine Mathieu,Nathalie Pons-Y-Moll,Jean François Bartoli,Frédéric Banse,Pierrette Battioni,Jean-Jacques Girerd,Daniel Mansuy +7 more
TL;DR: In this article, four iron(II) complexes, bearing hexa-, penta- or tetra-azadentate ligands, whose redox potentials vary from +280 to +1023mV (versus saturated calomel electrode), were compared as catalysts for the oxidation of various substrates by H2O2.
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Multiscale Model for a Metal–Organic Framework: High-Spin Rebound Mechanism in the Reaction of the Oxoiron(IV) Species of Fe-MOF-74
TL;DR: This paper performed ONIOM QM/MM calculations to understand how ethane is hydroxylated and ethanol is converted to acetaldehyde by an oxoiron(IV) species generated within an iron-containing metal-organic framework called Fe-MOF-74.
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Mild oxidation of styrene and its derivatives catalyzed by ionic manganese porphyrin embedded in a similar structured ionic liquid
TL;DR: In this article, the ionic manganese porphyrin (1c) with a pyridinium tag embedded in a POR-based ionic liquid, [BPy][BF4], efficiently catalyzed the oxidation of styrene and its derivatives under mild conditions, affording high activity/oxide selectivity.
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Silica supported Mn(Br8TPP)Cl and Mn(TPP)Cl as efficient and reusable catalysts for selective hydrocarbon oxidation under various reaction conditions: The effect of substituted bromines on the catalytic activity and reusability
Majid Moghadam,Valiollah Mirkhani,Shahram Tangestaninejad,Iraj Mohammdpoor-Baltork,Hadi Kargar +4 more
TL;DR: The imidazole-modified silica (SiIm) was used for immobilization of octabromotetraphenylporphyrinatomanganese(III) chloride, Mn(Br 8 TPP)Cl, and tetraphenymethylporphyrinamide(III), Mn(TPP)Cl as discussed by the authors.