Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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The oxidation of ethylbenzene and other alkylaromatics by dioxygen catalysed by iron(III) tetrakis(pentafluorophenyl)porphyrin and related iron porphyrins
TL;DR: In this article, a free radical autoxidation mechanism was proposed for the degradation of the porphyrin ligand with 1-phenylethoxyl, acetophenone, and 1-phylperoxyl radicals.
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Selective oxidation of aliphatic C-H bonds in the synthesis of complex molecules.
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New Insights into the Visible-Light-Induced DNA Cleavage Activity of Dipyridoquinoxaline Complexes of Bivalent 3d-Metal Ions
Mithun Roy,Biswarup Pathak,Ashis K. Patra,Eluvathingal D. Jemmis,Munirathinam Nethaji,Akhil R. Chakravarty +5 more
TL;DR: The theoretical data predict that the photoredox pathway is favorable for the 3d7-CoII and 3d9-CuII complexes to exhibit DNA cleavage activity, while the analogous 3d6-FeII and3d8-NiII complexes are energetically unfavorable for the exhibition of such activity under visible light.
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Catalytic activity of nitro- and carboxy-substituted iron porphyrins in hydrocarbon oxidation: Homogeneous solution and supported systems
TL;DR: A series of iron(III)porphyrins containing NO2-substituents in the meso-ortho-phenyl or COOH substituent in the FeP rings (FeP) have been used to catalyse hydrocarbon oxidation by iodosylbenzene as mentioned in this paper.
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Catalytic asymmetric sulfoxidation by chiral manganese complexes: acetylacetonate anions as chirality switches.
TL;DR: An interesting "chirality switch" effect by the achiral acac anion reversing the enantioselectivity of the complex [Mn(1)(ClO(4))(2)] from the S to the R sulfoxide enantiomer is observed.