Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Photochemical p-450 oxygenation of cyclohexene with water sensitized by dihydroxy-coordinated (tetraphenylporphyrinato)antimony(v) hexafluorophosphate
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Hemoprotein Models Based on a Covalent Helix–Heme–Helix Sandwich: 1. Design, Synthesis, and Characterization
Flavia Nastri,Angela Lombardi,Giancarlo Morelli,Ornella Maglio,Gabriella D'Auria,Carlo Pedone,Vincenzo Pavone +6 more
TL;DR: UV/Visible spectroscopic characterization in buffered 2,2,2-trifluoroethanol/water solution proves low-spin bis(his-tidine) iron(III) coordination; circular dichroism (CD) measurements show an α-helical conformation for the peptide moieties.
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Production of a Putative Iron(V)−Oxocorrole Species by Photo-Disproportionation of a Bis-Corrole−Diiron(IV)−μ-Oxo Dimer: Implication for a Green Oxidation Catalyst
TL;DR: Air oxidation of the corrole-iron(III) species regenerated the bis-corrole-diiron(IV)-mu-oxo dimer, allowing the development of a photocatalytic method for organic oxidations using molecular oxygen and visible light.
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A novel catalysis of N-hydroxyphthalimide (NHPI) combined with Co(acac)n (n = 2 or 3) in the oxidation of organic substrates with molecular oxygen
TL;DR: In this paper, a combination of NHPI with Co(acac) n (n = 2 or 3) was found to be efficient for the oxidation of cycloalkanes, polycyclic alkanes and alkylbenzenes.
Journal ArticleDOI
Heterogeneous Photo-Fenton Degradation of an Azo Dye in Aqueous H2O2/Iron Oxide Dispersions at Neutral pHs.
TL;DR: In this article, the photodegradation of Mordant Yellow 10 (MY10) in aqueous dispersions of H2O2/hematite (α-Fe2O3), goethite (β-FeOOH), and akaganeite ( β-FeOH) under UV-light irradiation was examined.