Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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New soluble peripherally tetra-substituted Co(II), Fe(II) phthalocyanines: Synthesis, spectroscopic characterization and their catalytic activity in cyclohexene oxidation
TL;DR: In this paper, an iron-II and cobalt-II phthalocyanine complexes were obtained by the reaction of the phthalonitrile derivative 3 with n-pentanol in a standard Schlenk tube in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU).
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Spectroscopic observation of iodosylarene metalloporphyrin adducts and manganese(V)-oxo porphyrin species in a cytochrome P450 analogue
TL;DR: The direct ultraviolet-visible spectroscopic observation of the soluble iodosylarene-manganese porphyrin adduct following catalytic oxidation using 2,4,6-tri-tert-butylphenol as the reductant provides insight into the mechanism of oxygen transfer within the haem-containing enzymatic systems.
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Diastereoselective epoxidation of allylic alcohols with hydrogen peroxide catalyzed by titanium-containing zeolites or methyltrioxorhenium versus stoichiometric oxidation with dimethyldioxirane: Clues on the active species in the zeolite lattice
Waldemar Adam,Avelino Corma,Agustín Martínez,Catherine M. Mitchell,T. Indrasena Reddy,Michael Renz,Alexander K. Smerz +6 more
TL;DR: In this article, the diastereomeric ratios of the titanium-containing zeolites with those for meta-chloroperbenzoic acid showed a good correspondence which suggests that the active species for the oxygen transfer in the epoxidations for zeolite is peracid-rather than peroxo-type.
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Spin State Energetics and Oxyl Character of Mn-Oxo Porphyrins by Multiconfigurational ab Initio Calculations: Implications on Reactivity
Sergio Augusto Venturinelli Jannuzzi,Sergio Augusto Venturinelli Jannuzzi,Quan Manh Phung,Alex Domingo,André Luiz Barboza Formiga,Kristine Pierloot +5 more
TL;DR: The RASPT2 results were used as a benchmark for the description of excited state energetics and Mn-O oxyl character with a wide range of pure and hybrid density functionals.
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Metallo-Deuteroporphyrin as a Biomimetic Catalyst for the Catalytic Oxidation of Lignin to Aromatics
Chenjie Zhu,Weiwei Ding,Shen Tao,Chenglun Tang,Chenguo Sun,Shichao Xu,Yong Chen,Jinglan Wu,Hanjie Ying +8 more
TL;DR: It was found that the modified cobalt deuteroporphyrin that has no substituents at the meso sites but does have the disulfide linkage in the propionate side chains at the β sites exhibited much higher activity and stability than the synthetic tetraphenylporphyrin.