Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Journal ArticleDOI
Fluorous Biphasic Catalytic Oxidation of Alkenes and Aldehydes with Air and 2‐Methylpropanal in the Presence of (β‐Perfluoroalkylated tetraphenylporphyrin)cobalt Complexes
TL;DR: A simple and facile fluorous biphasic catalytic oxidation of alkenes and aldehydes with 1 atm of air and 2-methylpropanal in the presence of the (beta-perfluoroalkylated tetraphenylporphyrin) cobalt complexes [Co{TPP(C8F17)(4)}] (Co2) has been demonstrated for the first time as discussed by the authors.
Journal ArticleDOI
Die CH‐Bindungen der Zuckerbausteine von DNA als Angriffspunkte für chemische Nucleasen und Wirkstoffe
TL;DR: In this paper, a Ubersicht befast sich with den molekularen Aspekten der DNA-Spaltung durch synthetische chemische Nucleasen (Ubergangsmetallkomplexe with Redoxeigenschaften and Affinitat zu DNA) and naturliche Wirkstoffe (cytotoxische Agentien wie Bleomycine and Endiine).
Journal ArticleDOI
Novel synthesis of 5,10,15,20-tetraarylporphyrins using high-valent transition metal salts
TL;DR: In this article, a new synthesis of porphyrins from pyrrole and substituted benzaldehydes, using high-valent transition metal salts [VOCl3, VO(OEt)Cl2, VOOPri)Cl 2, TiCl4 and Mn(OAc)3] as aromatizing agents was described.
Book ChapterDOI
112 – Single-Atom Bridged Dinuclear Metal Complexes with Emphasis on Phthalocyanine Systems
Journal ArticleDOI
Simple metal oxides as efficient heterogeneous catalysts for epoxidation of alkenes by molecular oxygen
TL;DR: Magnetite iron oxide (Fe3O4) has been found to be an efficient heterogeneous catalyst for the epoxidation of alkenes by molecular oxygen in the absence of a sacrificial reductant among various tran...