Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Journal ArticleDOI
The mechanism of enzymatic and biomimetic oxidations of aromatic sulfides and sulfoxides
TL;DR: In this article, the authors show that biomimetic and enzymatic oxidations of benzyl sulfides and sulfoxides lead to products (sulfoxides or sulfones) different from those obtained with bona fide electron transfer oxidations (products of CH and/or S bond cleavage), which suggests the operation of an oxygen transfer mechanism.
Journal ArticleDOI
A novel catalytic system for oxygenation with molecular oxygen induced by transition metal complexes with a multidentate N-heterocyclic podand ligand
Toshikazu Hirao,Toshiyuki Moriuchi,Takuji Ishikawa,Kouichirou Nishimura,Satoshi Mikami,Yoshiki Ohshiro,Isao Ikeda +6 more
TL;DR: In this paper, an efficient system for the catalytic epoxidation reaction of olefins with molecular oxygen was achieved by the utilization of FeCl 2 and the N -heterocyclic podand ligand, N,N′ -bis{2-(4-imidazolyl)ethyl}-2,6-pyridinedicarboxamide (BIPA), without the need for a co-reductant.
Journal ArticleDOI
Potential energy curves and electronic structure of 3d transition metal hydrides and their cations
Satyender Goel,Artëm E. Masunov +1 more
TL;DR: The performance of two exchange-correlation functionals, Boese-Martin for kinetics and Tao-Perdew-Staroverov-Scuseria (TPSS), in predicting bond lengths and energetics, electronic structures, dipole moments, and ionization potentials is evaluated.
Journal ArticleDOI
The strong influence of structures around titanium centers in dimeric mono-, di-, and tri-titanium(IV)-substituted Keggin polyoxotungstates on the catalytic epoxidation of alkenes with H2O2
TL;DR: In this paper, it was shown that tri-titanium(IV)-substituted Keggin polyoxotungstates (α-PTiW11O39)2O]8− (1), [(α-1,2-PW10Ti2O38]2O2]10− (2), and [(α 1,2,3-PTI3W9O37)2 O3]12− (3) catalyzed the epoxidation of cyclooctene, cyclohexene, and 1
Book ChapterDOI
Polyoxometalates in Catalytic Selective Homogeneous Oxygenation and Anti-HIV Chemotherapy
TL;DR: In this paper, a review concentrates on two areas of intense research interest involving polyoxometalates, homogeneous catalysis and medicine, and a general compilation is given in Table I of the literature reactions involving 21 TMSP complexes, 10 oxidants, five classes of substrates and 10 solvent systems.