Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Electrogenerated chemiluminescence of sterically hindered porphyrins in aqueous media
TL;DR: A sterically hindered water-soluble porphyrin, tetrakis(3-sulfonatomesityl)porphyrin (H2TSMP), could form stable radical cation in aqueous media after electrochemical one electron oxidation as discussed by the authors.
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Low potential detection of indole-3-acetic acid based on the peroxidase-like activity of hemin/reduced graphene oxide nanocomposite.
TL;DR: An amperometric sensor was firstly established for the detection of indole-3-acetic acid (IAA) at low potential based on the hemin/reduced graphene oxide (hemin/rGO) composite and provided a new method for IAA detection.
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Polystyrene-bound imidazole as a heterogeneous axial ligand for Mn(TPP)Cl and its use as hydrocarbon monooxygenation catalyst in the alkene epoxidation and alkane hydroxylation with sodium periodate under various reaction conditions
Majid Moghadam,Shahram Tangestaninejad,Valiollah Mirkhani,Hadi Kargar,Hedyeh Komeili-Isfahani +4 more
TL;DR: Polystyrene-bound imidazole (PSI) is not only a heterogeneous axial base but also a support for immobilization of tetraphenylporphyrinatomanganese (III) chloride as discussed by the authors.
Journal ArticleDOI
Reactivity of the Coordinated Hydroperoxo Ligand.
TL;DR: The reactivity of the hydroperoxo complex [Co(CN)(5)OOH](3)(-) has been studied in aqueous solution and the reaction is acid catalyzed and is proposed to take place via nucleophilic attack of sulfur on the proximal oxygen of thehydrogen peroxide ligand with concerted loss of water.
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Photochemical oxidation of a manganese(III) complex with oxygen and toluene derivatives to form a manganese(V)-oxo complex.
Jieun Jung,Kei Ohkubo,Katharine A. Prokop-Prigge,Heather M. Neu,David P. Goldberg,Shunichi Fukuzumi,Shunichi Fukuzumi +6 more
TL;DR: The data suggest a new catalytic method is accessible for the selective oxidation of C-H bonds with O2 and light, and the first evidence for catalytic oxidation of H2O bonds was obtained with 10-methyl-9,10-dihydroacridine as a substrate.