Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Oxidation of aldehydes using silica-supported Co(II)-substituted heteropolyacid
TL;DR: In this paper, a supported Co(II)-substituted heteropolyacid salt, Cs6H2P2W17O61Co·OH2, on silica was prepared and characterized by BET surface area measurements, thermal analysis (TGA/DTA) and infrared spectroscopy.
Journal ArticleDOI
Mechanism of catalytic decomposition of pentachlorophenol by a highly recyclable heterogeneous SiO2–[Fe-porphyrin] catalyst
TL;DR: In this paper, the electron spin density of the 1u cation radical (Por + ) is mainly localised on the tetrapyrole frame, and this results in the observed weak magnetic coupling between the S ǫ = 1 oxo-ferryl moiety (Fe IV O) and the s à à Á = 1/2 porphyrin cation radicals (POR + ).
Journal ArticleDOI
Biomimetic metalloporphines and metalloporphyrins as potential tools for delignification: Molecular mechanisms and application perspectives
TL;DR: In this article, a review of lignin biosynthesis and structure is depicted; also the commonly used industrial protocols for pulp delignification are described, with special emphasis on their molecular aspects.
Journal ArticleDOI
Oxidation of phenol and hydroquinone catalysed by copper(II) and oxovanadium(IV) complexes of N,N′-bis(salicyledene)diethylenetriamine (H2saldien) covalently bonded to chloromethylated polystyrene
Mannar R. Maurya,Sweta Sikarwar +1 more
TL;DR: In this article, a polymer-anchored complex PS-[VO(saldien)] was found to be a suitable catalyst for the synthesis of phenol and hydroquinone.