Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Mild and Efficient Flavin-Catalyzed H2O2 Oxidation of Tertiary Amines to Amine N-Oxides
TL;DR: A mild and highly effective H2O2 oxidation of tertiary amines has been developed by the use of flavin catalysis as discussed by the authors, where eight aliphatic amines were oxidized to their corresponding N-oxides in fast and sel...
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2,3,7,8,12,13,17,18-Octafluoro-5,10,15,20-tetraarylporphyrins and Their Zinc Complexes: First Spectroscopic, Electrochemical, and Structural Characterization of a Perfluorinated Tetraarylmetalloporphyrin
TL;DR: In this paper, the authors reported a convenient and general synthesis of β-octafluoroporphyrins bearing meso-tetraaryl substituents, including the first synthesis and full characterization of a perfluorinated tetraarylporphyrin.
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Photochemical generation of a highly reactive iron-oxo intermediate. A true iron(V)-oxo species?
TL;DR: A highly reactive iron-oxo transient was shown to be an oxo transfer agent in a preparative reaction with cis-cyclooctene and might be important in reactions of porphyrin-iron catalysts in the laboratory and in nature.
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Selective Catalytic Oxidation of Substrates That Bind to Metalloporphyrin Enzyme Mimics Carrying Two or Four Cyclodextrin Groups and Related Metallosalens
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Polymer supported vanadium and molybdenum complexes as potential catalysts for the oxidation and oxidative bromination of organic substrates.
TL;DR: The Schiff base (H2fsal-ohyba) derived from 3-formylsalicylic acid and o-hydroxybenzylamine has been covalently bonded to chloromethylated polystyrene cross-linked with 5% divinylbenzeneCross-linked complexes have been characterised by various techniques and their catalytic activities have been compared.