Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Zinc–Azatrane Complexes as Efficient Catalysts for the Conversion of Carbon Dioxide into Cyclic Carbonates
TL;DR: In this article, three Zn complexes based on the N4-tris(2-aminoethyl)-amine (tren) chelating ligand and presenting a C3 symmetrical axis have been synthesized and successfully applied in the coupling of CO2 with terminal and internal epoxides.
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Electron deficient nonplanar β-octachlorovanadylporphyrin as a highly efficient and selective epoxidation catalyst for olefins
TL;DR: VOTPPCl8 is stable after the catalytic reaction and doesn't form a μ-oxo dimer due to the highly electron deficient nonplanar porphyrin core and can be reused for several cycles.
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Synthesis of porphyrin@MOFs type catalysts through “one-pot” self-assembly
TL;DR: In this paper, the reaction of 1,1-bis-[3,5-bis(carboxy) phenoxy]methane (H 4 L) and CuCl 2 in the presence of meso-tetrakis[4-(nicotinoyloxy)phenyl]porphyrin (TNPP) and manganese complex of TNPP (MnTNPP), respectively, under solvothermal condition afforded CuTNPP@MOF and MnTNPP=MOF, microporous metal-organic materials containing neutral CuNPP
Journal ArticleDOI
Selective oxidation of hydrocarbons catalyzed by iron-containing heterogeneous catalysts
TL;DR: In this paper, the structure-reactivity relationships and the factors affecting the catalytic performances are discussed with the aim to uncover the requirements of the active iron sites in target-selective oxidation.
Journal ArticleDOI
Highly diastereoselective epoxidation of cholest-5-ene derivatives catalyzed by polymer-supported manganese(III) porphyrins
TL;DR: Manganese(III) 5,10,15-tris(tolyl)-20-(4-hydroxyphenyl) porphyrin covalently attached to Merrifield's peptide resin (MPR) was prepared as discussed by the authors.