Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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2,3,7,8,12,13,17,18‐Octafluoro‐5,10,15,20‐Tetraphenylporphyrin: First Synthesis and X‐Ray Crystal Structure of the ZnII Complex
TL;DR: In this article, a wide range of β-octafluoro-meso-arylated porphyrins, a new class of highly electron-deficient ligands, are potentially accessible from 3,4-difluoropyrrole, thus opening the door to efficient and robust oxidation catalysts.
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New manganese β-polynitroporphyrins as particularly efficient catalysts for biomimetic hydroxylation of aromatic compounds with H2O2
Jean-François Bartoli,Virginie Mouriès-Mansuy,Karine Le Barch-Ozette,Magali Palacio,Pierrette Battioni,Daniel Mansuy +5 more
TL;DR: A series of Mn porphyrins bearing one to eight β-nitro substituents were synthesized in high yield in three steps by using a new general method for selective nitration of a ============Zn(meso-tetraarylporphyrin) series exhibits a wide span of Mn(III)/Mn(II) redox potential from −290 to + 1150 mV.
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Hydrocarbon oxidation with iodosylbenzene catalysed by the sterically hindered iron(III) 5-(pentafluorophenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin in homogeneous solution and covalently bound to silica
TL;DR: A sterically hindered iron porphyrin has also been covalently bound by nucleophilic aromatic substitution to aminopropylated silica as mentioned in this paper, which is also stable towards oxidation but is less reactive than its homogeneous analogue.
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Synthesis and characterization of mononuclear ruthenium(III) pyridylamine complexes and mechanistic insights into their catalytic alkane functionalization with m-chloroperbenzoic acid.
Takahiko Kojima,Takahiko Kojima,Ken Ichi Hayashi,Shin Ya Iizuka,Fumito Tani,Yoshinori Naruta,Masaki Kawano,Yuji Ohashi,Yuichirou Hirai,Kei Ohkubo,Yoshihisa Matsuda,Shunichi Fukuzumi +11 more
TL;DR: These complexes act as effective catalysts for alkane functionalization in acetonitrile with m-chloroperbenzoic acid (mCPBA) as terminal oxidant at room temperature and can be altered significantly by the electronic effects of substituents on TPA ligands in terms of initial rates and turnover numbers.
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A Porphyrin Embedded in DNA
TL;DR: In this paper, the first porphyrin−nucleic acid conjugates bearing the porphrin embedded in the backbone of DNA were synthesized by automated solid-phase synthesis using a dimethoxytrityl-protected porphryin phosphoramidite and standard DNA building blocks.