Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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A Rational Basis for the Axial Ligand Effect in C−H Oxidation by [MnO(porphyrin)(X)]+ (X = H2O, OH−, O2−) from a DFT Study
TL;DR: The higher reactivity in the presence of acid noted by Groves and co-workers is thus rationalized by the preference for having X = H2O over OH(-) or O(2-), which is a key step in C-H oxidation.
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Reusable Porphyrinatoiron(III) Complex Supported on Activated Silica as an Efficient Heterogeneous Catalyst for a Facile, One-Pot, Selective Synthesis of 2-Arylbenzimidazole Derivatives in the Presence of Atmospheric Air as a “Green” Oxidant at Ambient Temperature
TL;DR: In this article, an efficient and highly selective synthesis of 2-arylbenzimidazoles by condensation of a wide range of aryl aldehydes bearing electron-donating or -withdrawing substituents and phenylenediamines in a single pot using a catalytic amount of (meso-tetrakis(o-chlorophenyl)porphyrinato)iron(III) chloride (5 mol-%) in excellent isolated yields is described.
Journal ArticleDOI
Direct Conversion of Cyclohexane into Adipic Acid with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide Combined with Mn(acac)2 and Co(OAc)2
TL;DR: In this paper, the NHPI-catalyzed oxidation of cyclohexane provides an attractive direct method which has long been desired in the chemical industry for the manufacturing of adipic acid.
Journal ArticleDOI
Highly Efficient Asymmetric Epoxidation of Alkenes with a D4-Symmetric Chiral Dichlororuthenium(IV) Porphyrin Catalyst
TL;DR: UV-vis and ESI-mass spectral analysis of the final reaction mixture revealed that a ruthenium-carbonyl species could have been formed during the catalytic reaction, leading to the apparent catalyst deactivation.