Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Reflections on Small Molecule Manganese Models that Seek to Mimic Photosynthetic Water Oxidation Chemistry
TL;DR: Recent advances in the study of the Oxygen Evolving Complex (OEC) of Photosystem II (PSII) include structural information attained from several X-ray crystallographic and spectroscopic investigations that offer better insight into the possible pathways used by PSII to drive photosynthetic water oxidation catalysis.
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Efficient Oxidative Dechlorination and Aromatic Ring Cleavage of Chlorinated Phenols Catalyzed by Iron Sulfophthalocyanine
TL;DR: This chemical system, consisting of an environmentally safe oxidant (H2O2) and an easily accessible catalyst (FePcS), can perform several key steps in the oxidative mineralization of TCP, a paradigm of recalcitrant pollutants.
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Two-state reactivity mechanisms of hydroxylation and epoxidation by cytochrome P-450 revealed by theory.
TL;DR: TSR is used to reconcile the dilemma of the consensus 'rebound mechanism' of alkane hydroxylation, which emerged from experimental studies of ultra-fast radical clocks.
Journal ArticleDOI
Selective C–H oxidation catalyzed by metalloporphyrins
TL;DR: Metalloporphyrins based on iron, manganese and ruthenium constitute a unique family of catalysts capable of generating highly reactive, but at the same time highly selective oxidants, thus mediating selective oxidations of saturated C-H bonds as discussed by the authors.