Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
About:
This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
Citations
More filters
Journal ArticleDOI
Manganese porphyrins incorporated in polydimethylsiloxane membranes: selective catalysts for the epoxidation of deactivated alkenes
TL;DR: In this article, the use of [5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato] manganese(III) chloride (TDCPP(Mn)Cl) in the presence of an axial ligand and embedded in a polydimethylsiloxane (PDMS) membrane is reported for the epoxidation of an enol with aqueous H 2 O 2.
Journal ArticleDOI
MnIIILx/t-BuOOH-induced activation of dioxygen for the oxygenation of cyclohexene
TL;DR: Several manganese (III) complexes in combination with tert-butyl hydroperoxide (t-BuOOH) activate dioxygen (O2) to oxygenate cyclohexene (c-C6H10) to its ketone, alcohol, and epoxide as discussed by the authors.
Journal ArticleDOI
β-Octafluoro-meso-tetraarylporphyrin iron complexes as catalysts for monooxygenation reactions
TL;DR: In this article, the stability and catalytic activity of the β-octafluoro-meso-tetraarylporphyrin iron complexes for cyclooctene epoxidation, cyclohexane and benzene hydroxylation by hydrogen peroxide and iodosylbenzene are studied.
Journal ArticleDOI
Mechanistic studies of selective catechol formation from o-methoxyphenols using a copper(II)–ascorbic acid–dioxygen system
TL;DR: In this paper, the authors studied the selective conversion of o-methoxyphenols to catechols using a Cu2+−ascorbic acid-O2 system.
Journal ArticleDOI
Tetracarboxyphenylporphyrin–Kaolinite Hybrid Materials as Efficient Catalysts and Antibacterial Agents
Analaura Lovo de Carvalho,Breno F. Ferreira,Carlos Henrique Gomes Martins,Eduardo J. Nassar,Shirley Nakagaki,Guilherme Sippel Machado,Vicente Rives,Raquel Trujillano,Miguel Vicente,Antonio Gil,Sophia A. Korili,Emerson H. de Faria,Katia J. Ciuffi +12 more
TL;DR: The preparation, characterization, and application in oxidation reactions and antibacterial activity of new biomimetic heterogeneous materials are reported in this paper, where Brazilian Sao Simao kaolinite has been functionalized with Fe(III)-[meso-tetrakis(tetracarboxyphenyl)porphinato], [FeTCPP].