Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Book ChapterDOI
Synthesis and coordination chemistry of noble metal porphyrins
TL;DR: In this paper, the main interest is devoted to noble metal complexes of porphyrins, but complexes of hydroporphyrin, porphrin analogs, homologs and phthalocyanines are also mentioned where appropriate.
Journal ArticleDOI
Manganese substituted Compound I of cytochrome P450 biomimetics: A comparative reactivity study of MnV-oxo versus MnIV-oxo species
Reza Latifi,Laleh Tahsini,Laleh Tahsini,Baharan Karamzadeh,Nasser Safari,Wonwoo Nam,Sam P. de Visser +6 more
TL;DR: This study shows that although both oxidants are capable of hydroxylating AcrH(2), the Mn(V)-oxo species is the more active oxidant and thermodynamic cycles that explain the reaction mechanisms and electron transfer processes are generalized.
Journal ArticleDOI
Oxidation of Safranine T in Aqueous Solution Using Fenton's Reagent: Involvement of an Fe(III) Chelate in the Catalytic Hydrogen Peroxide Oxidation of Safranine T
TL;DR: In this paper, the chemistry and kinetics of a basic dye, Safranine T (C. I. Basic Red 2), by the classic Fenton's reagent (Fe2+ and H2O2), were investigated.
Journal ArticleDOI
Electrospray tandem mass spectrometry of oxo complexes of chromium, manganese and tuthenium
TL;DR: In this article, the mass spectrum obtained from solution in acetonitrile shows the molecular ion as the base peak with a minimal degree of fragmentation, which is the case for many oxometal species including MnO4, Cr2O72, CrO3Cl, RuO4 and RuO2Cl3.
Journal ArticleDOI
Ultrafast relaxation times of metalloporphyrins by time-resolved degenerate four-wave mixing with incoherent light
D. Narayana Rao,S. Venugopal Rao,Francisco J. Aranda,D. Rao,Masato Nakashima,Joseph A. Akkara +5 more
TL;DR: In this paper, the authors present experimental results on the measurement of the population-relaxation times of the excited states of some metalloporphyrins such as zinc meso-tetra-phenylporphyrin (ZnmTPP), zinc mesoencetra (p-methoxyphenyl) tetrabenzporphrin (ZnmpTBP), tetratollyl porphrin(TTP).