Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Nonradical tetrabutylammonium monopersulfate oxidation of hydrocarbons catalyzed by [Mn3O4bipy4(H2O)2](ClO4)4
Jeremy Wessel,Robert H. Crabtree +1 more
TL;DR: Tetrabutylammonium monopersulfate (2NBu4HSO5·NBu 4HSO4· NBu 4 HSO4 · NBu4)2SO4 is an effective primary oxidant with a high tendency to promote oxo transfer rather than radical pathways in catalysis.
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Cytochrome P-450 model reactions: a kinetic study of epoxidation of alkenes by iron phthalocyanine
Nasser Safari,Farzad Bahadoran +1 more
TL;DR: A kinetic study for measuring the relative rate of the catalytic epoxidation of various alkenes has been employed based upon the disappearance of the 1,4-diphenylbutadiene as discussed by the authors.
Journal ArticleDOI
Robust and electron deficient oxidovanadium(IV) porphyrin catalysts for selective epoxidation and oxidative bromination reactions in aqueous media
TL;DR: In this paper, the acetonitrile coordinated porphyrin 1 is relatively planar whereas 2 is highly nonplanar as shown by their crystal structures and also by electrochemical studies.
Journal ArticleDOI
Efficient degradation of organic pollutants mediated by immobilized iron tetrasulfophthalocyanine under visible light irradiation
TL;DR: Supported iron tetrasulfophthalocyanine can efficiently catalyze the degradation of organic pollutants by H2O2 under visible light irradiation in an aqueous solution, and the catalyst can be easily recycled without apparent loss of activity.
Journal ArticleDOI
Synthesis and electrochemistry of cobalt β-halogenated meso-tetraphenylporphyrins containing a nitrosyl axial ligand. Crystal structure of (TPPBr4NO2)Co(NO)
Karl M. Kadish,Zhongping Ou,Xiaoyu Tan,Tristano Boschi,Donato Monti,Vincenzo Fares,Pietro Tagliatesta +6 more
TL;DR: In this paper, three new cobalt porphyrins, two of which are coordinated by a nitrosyl group, have been synthesized and characterized by spectral and electrochemical methods.