Journal ArticleDOI
Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage
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This article is published in Chemical Reviews.The article was published on 1992-09-01. It has received 1930 citations till now.read more
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Selective catalytic oxidation of hydrocarbons. New prospects
TL;DR: In this paper, the authors focused on the method proposed by the authors for controlling the catalytic activity of transition metal complexes in hydrocarbon (in particular, alkylarene) oxidation with molecular oxygen.
Journal ArticleDOI
Synthesis of new aminoporphyrins via palladium-catalysed cross-coupling reactions
TL;DR: In this paper, a method for the preparation of a variety of amino substituted zinc porphyrins using palladium-catalysed intermolecular carbon-nitrogen coupling reactions between haloporphyrin and a series of amino derivatives is reported.
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Manganeseporphyrin-catalyzed alkenes epoxidation by iodobenzene diacetate in a room temperature ionic liquid
Zhen Li,Chun-Gu Xia,Min Ji +2 more
TL;DR: In this article, a catalytic epoxidation of alkenes with iodobenzene diacetate by the manganeseporphyrin in environmentally benign and ambient temperature ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6) has been studied.
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Effect of the Protein Matrix of Cytochrome c in Suppressing the Inherent Peroxidase Activity of Its Heme Prosthetic Group
TL;DR: This work quantifies the suppression of the inherent peroxidase activity of heme by the protein matrix of cytochrome c and shows that the peroxide activity of unfolded cytc is similar to that of microperoxid enzyme-8 (MP-8).
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Visible-light-assisted generation of high-valent iron-oxo species anchored axially on g-C3N4 for efficient degradation of organic pollutants
TL;DR: In this article, a novel visible-light-assisted advanced oxidation process based on high-valent iron species (Fe(IV) O) was fabricated over graphitic carbon nitride (g-C3N4) that was coordinated to iron hexadecachlorophthalocyanine (FePcCl16) through imidazole ligands.