Paul Scherrer Institute

About: Paul Scherrer Institute is a facility organization based out in Villigen, Switzerland. It is known for research contribution in the topics: Neutron & Large Hadron Collider. The organization has 9248 authors who have published 23984 publications receiving 890129 citations. The organization is also known as: PSI.

Molecular-Based Magnetism in Bimetallic Two-Dimensional Oxalate-Bridged Networks. An X-ray and Neutron Diffraction Study.

Abstract: Bimetallic, oxalate-bridged compounds with bi- and trivalent transition metals comprise a class of layered materials which express a large variety in their molecular-based magnetic behavior. Because of this, the availability of the corresponding single-crystal structural data is essential to the successful interpretation of the experimental magnetic results. We report in this paper the crystal structure and magnetic properties of the ferromagnetic compound {[N(n-C3H7)4][MnIICrIII(C2O4)3]}n (1), the crystal structure of the antiferromagnetic compound {[N(n-C4H9)4][MnIIFeIII(C2O4)3]}n (2), and the results of a neutron diffraction study of a polycrystalline sample of the ferromagnetic compound {[P(C6D5)4][MnIICrIII(C2O4)3]}n (3). Crystal data: 1, rhombohedral, R3c, a = 9.363(3) A, c = 49.207(27) A, Z = 6; 2, hexagonal, P63, a = 9.482(2) A, c = 17.827(8) A, Z = 2. The structures consist of anionic, two-dimensional, honeycomb networks formed by the oxalate-bridged metal ions, interleaved by the templating cations. Single-crystal field dependent magnetization measurements as well as elastic neutron scattering experiments on the manganese(II)−chromium(III) samples show the existence of long-range ferromagnetic ordering behavior below Tc = 6 K. The magnetic structure corresponds to an alignment of the spins perpendicular to the network layers. In contrast, the manganese(II)−iron(III) compound expresses a two-dimensional antiferromagnetic ordering.

Review: Laser-Ablation Propulsion

Abstract: LASER ablation propulsion (LAP) is a major new electric propulsion concept with a 35-year history. In LAP, an intense laser beam [pulsed or continuous wave (CW)] strikes a condensedmatter surface (solid or liquid) and produces a jet of vapor or plasma. Just as in a chemical rocket, thrust is produced by the resulting reaction force on the surface. Spacecraft and other objects can be propelled in this way. In some circumstances, there are advantages for this technique compared with other chemical and electric propulsion schemes. It is difficult to make a performance metric for LAP, because only a few of its applications are beyond the research phase and because it can be applied in widely different circumstances that would require entirely different metrics. These applications range from milliwatt-average-power satellite attitude-correction thrusters through kilowatt-average-power systems for reentering near-Earth space debris and megawatt-to-gigawatt systems for direct launch to lowEarth orbit (LEO). We assume an electric laser rather than a gas-dynamic or chemical laser driving the ablation, to emphasize the performance as an electric thruster. How is it possible for moderate laser electrical efficiency to givevery high electrical efficiency? Because laser energy can be used to drive an exothermic reaction in the target material controlled by the laser input, and electrical efficiency only measures the ratio of exhaust power to electrical power. This distinction may seem artificial, but electrical efficiency is a key parameter for space applications, in which electrical power is at a premium. The laser system involved in LAP may be remote from the propelled object (on another spacecraft or planet-based), for example, in laser-induced space-debris reentry or payload launch to low planetary orbit. In other applications (e.g., the laser–plasma microthruster that we will describe), a lightweight laser is part of the propulsion engine onboard the spacecraft.

Relation between rock uplift and denudation from cosmogenic nuclides in river sediment in the Central Alps of Switzerland

Abstract: [1] A north-south traverse through the Swiss Central Alps reveals that denudation rates correlate with recent rock uplift rates in both magnitude and spatial distribution. This result emerges from a study of in situ–produced cosmogenic 10Be in riverborne quartz in Central Alpine catchments. As a prerequisite, we took care to investigate the potential influence of shielding from cosmic rays due to snow, glaciers, and topographic obstructions; to calculate a possible memory from Last Glacial Maximum (LGM) glaciation; and to identify a watershed size that is appropriate for systematic sampling. Mean denudation rates are 0.27 ± 0.14 mm/a for the Alpine foreland and 0.9 ± 0.3 mm/a for the crystalline Central Alps. The measured cosmogenic nuclide-derived denudation rates are in good agreement with post-LGM lake infill rates and are about twice as high as denudation rates from apatite fission track ages that record denudation from 9 to 5 Ma. In general, denudation rates are high in areas of high topography and high crustal thickness. The similarity in the spatial distribution and magnitude of denudation rates and those of rock uplift rates can be interpreted in several ways: (1) Postglacial rebound or climate change has introduced a transient change in which both uplift and denudation follow each other with a short lag time; (2) the amplitude of glacial to interglacial changes in both is small and is contained in the scatter of the data; (3) both are driven by ongoing convergence where their similarity might hint at some form of long-term quasi steady state; or (4) enhanced continuous Quaternary erosion and isostatic compensation of the mass removed accounts for the distribution of present-day rock uplift.

Loading-dependent elemental composition of α-pinene SOA particles

Abstract: . The chemical composition of secondary organic aerosol (SOA) particles, formed by the dark ozonolysis of α-pinene, was characterized by a high-resolution time-of-flight aerosol mass spectrometer. The experiments were conducted using a continuous-flow chamber, allowing the particle mass loading and chemical composition to be maintained for several days. The organic portion of the particle mass loading was varied from 0.5 to >140 μg/m3 by adjusting the concentration of reacted α-pinene from 0.9 to 91.1 ppbv. The mass spectra of the organic material changed with loading. For loadings below 5 μg/m3 the unit-mass-resolution m/z 44 (CO2+) signal intensity exceeded that of m/z 43 (predominantly C2H3O+), suggesting more oxygenated organic material at lower loadings. The composition varied more for lower loadings (0.5 to 15 μg/m3) compared to higher loadings (15 to >140 μg/m3). The high-resolution mass spectra showed that from >140 to 0.5 μg/m3 the mass percentage of fragments containing carbon and oxygen (CxHyOz+) monotonically increased from 48% to 54%. Correspondingly, the mass percentage of fragments representing CxHy+ decreased from 52% to 46%, and the atomic oxygen-to-carbon ratio increased from 0.29 to 0.45. The atomic ratios were accurately parameterized by a four-product basis set of decadal volatility (viz. 0.1, 1.0, 10, 100 μg/m3) employing products having empirical formulas of C1H1.32O0.48, C1H1.36O0.39, C1H1.57O0.24, and C1H1.76O0.14. These findings suggest considerable caution is warranted in the extrapolation of laboratory results that were obtained under conditions of relatively high loading (i.e., >15 μg/m3) to modeling applications relevant to the atmosphere, for which loadings of 0.1 to 20 μg/m3 are typical. For the lowest loadings, the particle mass spectra resembled observations reported in the literature for some atmospheric particles.