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Valence band splittings and band offsets of AlN, GaN and InN.

Su-Huai Wei, +1 more
TLDR
In this article, first principles electronic structure calculations on wurtzite AlN, GaN, and InN reveal crystal field splitting parameters ΔCF of −217, 42, and 41 meV, respectively.
Abstract
First‐principles electronic structure calculations on wurtzite AlN, GaN, and InN reveal crystal‐field splitting parameters ΔCF of −217, 42, and 41 meV, respectively, and spin–orbit splitting parameters Δ0 of 19, 13, and 1 meV, respectively. In the zinc blende structure ΔCF≡0 and Δ0 are 19, 15, and 6 meV, respectively. The unstrained AlN/GaN, GaN/InN, and AlN/InN valence band offsets for the wurtzite (zinc blende) materials are 0.81 (0.84), 0.48 (0.26), and 1.25 (1.04) eV, respectively. The trends in these spectroscopic quantities are discussed and recent experimental findings are analyzed in light of these predictions.

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Citations
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Journal ArticleDOI

Origin of exciton emissions from an AlN p-n junction light-emitting diode

TL;DR: In this article, an AlN light-emitting diode with an improved emission efficiency of 1×10−4% was observed at 5.94 eV and 6.10 eV by current injection.
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Optimization of the active-Layer structure for the deep-UV AlGaN light-emitting diodes

TL;DR: In this article, the dependence of the active layer structure on the performance of the deep-UV AlGaN light-emitting diodes was theoretically investigated with an APSYS simulation program.
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Spin–orbit splittings in AlN, GaN and InN

TL;DR: In this paper, the spin-orbit splittings of the top valence bands of AlN, GaN, and InN crystallized in the zinc blendestructure were calculated using the LMTO-LDA method.
References
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Journal ArticleDOI

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TL;DR: In this article, the authors present a comprehensive, up-to-date compilation of band parameters for the technologically important III-V zinc blende and wurtzite compound semiconductors.
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When group-III nitrides go infrared: New properties and perspectives

TL;DR: In this paper, the bandgap of InN was revised from 1.9 eV to a much narrower value of 0.64 eV, which is the smallest bandgap known to date.
Journal ArticleDOI

Monte Carlo simulation of electron transport in the III-nitride wurtzite phase materials system: binaries and ternaries

TL;DR: In this paper, a comprehensive study of the transport dynamics of electrons in the ternary compounds, Al/sub x/Ga/sub 1-x/N and In/sub ng/g/ng/s/n g/n/g n/g 1.x/n, is presented, which includes all of the major scattering mechanisms.
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