Institution
Nanjing University
Education•Nanjing, China•
About: Nanjing University is a education organization based out in Nanjing, China. It is known for research contribution in the topics: Catalysis & Adsorption. The organization has 85961 authors who have published 105504 publications receiving 2289036 citations. The organization is also known as: NJU & Nanking University.
Topics: Catalysis, Adsorption, Population, Computer science, Thin film
Papers published on a yearly basis
Papers
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TL;DR: Infiltration of a conducting polymer hydrogel into Si-based anodes results in a well-connected three-dimensional network structure consisting of Si nanoparticles conformally coated by the conducting polymer, demonstrating a cycle life of 5,000 cycles with over 90% capacity retention at current density.
Abstract: Silicon has a high-specific capacity as an anode material for Li-ion batteries, and much research has been focused on overcoming the poor cycling stability issue associated with its large volume changes during charging and discharging processes, mostly through nanostructured material design. Here we report incorporation of a conducting polymer hydrogel into Si-based anodes: the hydrogel is polymerized in-situ, resulting in a well-connected three-dimensional network structure consisting of Si nanoparticles conformally coated by the conducting polymer. Such a hierarchical hydrogel framework combines multiple advantageous features, including a continuous electrically conductive polyaniline network, binding with the Si surface through either the crosslinker hydrogen bonding with phytic acid or electrostatic interaction with the positively charged polymer, and porous space for volume expansion of Si particles. With this anode, we demonstrate a cycle life of 5,000 cycles with over 90% capacity retention at current density of 6.0 A g(-1).
1,181 citations
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TL;DR: In this article, the authors used the Very Long Baseline Array and the Japanese VLBI Exploration of Radio Astronomy project to measure trigonometric parallaxes and proper motions of masers found in high-mass star-forming regions across the Milky Way.
Abstract: We are using the Very Long Baseline Array and the Japanese VLBI Exploration of Radio Astronomy project to measure trigonometric parallaxes and proper motions of masers found in high-mass star-forming regions across the Milky Way. Early results from 18 sources locate several spiral arms. The Perseus spiral arm has a pitch angle of 16 degrees +/- 3 degrees, which favors four rather than two spiral arms for the Galaxy. Combining positions, distances, proper motions, and radial velocities yields complete three-dimensional kinematic information. We find that star-forming regions on average are orbiting the Galaxy approximate to 15 km s(-1) slower than expected for circular orbits. By fitting the measurements to a model of the Galaxy, we estimate the distance to the Galactic center R(0) = 8.4 +/- 0.6 kpc and a circular rotation speed Theta(0) = 254 +/- 16 km s(-1). The ratio Theta(0)/R(0) can be determined to higher accuracy than either parameter individually, and we find it to be 30.3 +/- 0.9 km s(-1) kpc(-1), in good agreement with the angular rotation rate determined from the proper motion of Sgr A*. The data favor a rotation curve for the Galaxy that is nearly flat or slightly rising with Galactocentric distance. Kinematic distances are generally too large, sometimes by factors greater than 2; they can be brought into better agreement with the trigonometric parallaxes by increasing Theta(0)/R(0) from the IAU recommended value of 25.9 km s(-1) kpc(-1) to a value near 30 km s(-1) kpc(-1). We offer a "revised" prescription for calculating kinematic distances and their uncertainties, as well as a new approach for defining Galactic coordinates. Finally, our estimates of Theta(0) and Theta(0)/R(0), when coupled with direct estimates of R(0), provide evidence that the rotation curve of the Milky Way is similar to that of the Andromeda galaxy, suggesting that the dark matter halos of these two dominant Local Group galaxy are comparably massive.
1,167 citations
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TL;DR: Recent progress in addressing stability, how to allow mass production, and how to maintain uniformity of large-area films are reviewed, and the remaining challenges along the pathway to their commercialization are discussed.
Abstract: BACKGROUND Perovskite solar cells (PSCs) have attracted intensive attention because of their ever-increasing power conversion efficiency (PCE), low-cost materials constituents, and simple solution fabrication process. Initiated in 2009 with an efficiency of 3.8%, PSCs have now achieved a lab-scale power conversion efficiency of 23.3%, rivaling the performance of commercial multicrystalline silicon solar cells, as well as copper indium gallium selenide (CIGS) and cadmium telluride (CdTe) thin-film solar cells. Thousands of articles related to PSCs have been published each year since 2015, highlighting PSCs as a topic of intense interest in photovoltaics (PV) research. With high efficiencies achieved in lab devices, stability and remaining challenges in upscaling the manufacture of PSCs are two critical concerns that must be addressed on the path to PSC commercialization. ADVANCES We review recent progress in PSCs and discuss the remaining challenges along the pathway to their commercialization. Device configurations of PSCs (see the figure) include mesoscopic formal (n-i-p) and inverted (p-i-n) structures, planar formal and inverted structures, and the printable triple mesoscopic structures. PCEs of devices that use these structures have advanced rapidly in the case of small-area devices (~0.1 cm 2 ). PSCs are also attracting attention as top cells for the construction of tandem solar cells with existing mature PV technologies to increase efficiency beyond the Shockley-Queisser limit of single-junction devices. The stability of PSCs has attracted much well-deserved attention of late, and notable progress has been made in the past few years. PSCs have recently achieved exhibited lifetimes of 10,000 hours under 1 sun (1 kW/m 2 ) illumination with an ultraviolet filter at a stabilized temperature of 55°C and at short-circuit conditions for a printable triple mesoscopic PSCs. This irradiation is equivalent to the total irradiation of 10 years of outdoor use in most of Europe. However, within the PSC community, standard testing protocols require further development. In addition, transparency in reporting standards on stability tests needs to be improved; this can be achieved by providing both initial photovoltaic performance and normalization parameters. The upscaling of PSCs has also progressed steadily, leading to PSC mini-modules, standard-sized modules, and power systems. PV companies have set out to manufacture large-area PSC modules (see the figure), and a 110-m 2 perovskite PV system with screen-printed triple mesoscopic PSC modules was recently debuted. Studies of these increased-area modules and systems will promote the development of PSCs toward commercialization. PSC research is expanding to cover fundamental topics on materials and lab-sized cells, as well as to address issues of industrial-scale manufacturing and deployment. OUTLOOK The PV market has been continuously expanding in recent years, bringing opportunities for new PV technologies of which PSCs are promising candidates. It is imperative to achieve a low cost per watt, which means that both efficiency and lifetime need improvement relative to current parameters. The efficiency gap between lab cells and industrial modules has seen impressive reductions in crystalline silicon; PSCs must similarly enlarge module areas to the panel level and need to achieve lifetimes comparable to those of legacy PV technologies. Other improvements will need to include industry-scale electronic-grade films, recycling methods to address concerns regarding lead toxicity, and the adoption of standardized testing protocols to predict the operation lifetime of PSCs. Modules will need to endure light-induced degradation, potential-induced degradation, partial-shade stress, and mechanical shock. The field can benefit from lessons learned during the development of mature PV technologies as it strives to define, and overcome, the hurdles to PSC commercial impact.
1,160 citations
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TL;DR: In this paper, an overview of organic electrode materials, including their fundamental knowledge, development history and perspective applications, is provided. And the authors elaborate in detail various organics with different structures, including conducting polymers, organodisulfides, thioethers, nitroxyl radical polymers and conjugated carbonyl compounds.
Abstract: As an alternative to conventional inorganic intercalation electrode materials, organic electrode materials are promising candidates for the next generation of sustainable and versatile energy storage devices. In this paper we provide an overview of organic electrode materials, including their fundamental knowledge, development history and perspective applications. Based on different organics including n-type, p-type and bipolar, we firstly analyzed their working principles, reaction mechanisms, electrochemical performances, advantages and challenges. To understand the development history and trends in organic electrode materials, we elaborate in detail various organics with different structures, including conducting polymers, organodisulfides, thioethers, nitroxyl radical polymers and conjugated carbonyl compounds. The high electrochemical performance, in addition with the unique features of organics such as flexibility, processability and structure diversity, provide them great perspective in various energy storage devices, including rechargeable Li/Na batteries, supercapacitors, thin film batteries, aqueous rechargeable batteries, redox flow batteries and even all-organic batteries. It is expected that organic electrode materials will show their talents in the “post Li-ion battery” era, towards cheap, green, sustainable and versatile energy storage devices.
1,156 citations
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TL;DR: Tao et al. as discussed by the authors discuss the development of the key components for achieving high-performance evaporation, including solar absorbers and structures, thermal insulators and thermal concentrators.
Abstract: As a ubiquitous solar-thermal energy conversion process, solar-driven evaporation has attracted tremendous research attention owing to its high conversion efficiency of solar energy and transformative industrial potential. In recent years, solar-driven interfacial evaporation by localization of solar-thermal energy conversion to the air/liquid interface has been proposed as a promising alternative to conventional bulk heating-based evaporation, potentially reducing thermal losses and improving energy conversion efficiency. In this Review, we discuss the development of the key components for achieving high-performance evaporation, including solar absorbers, evaporation structures, thermal insulators and thermal concentrators, and discuss how they improve the performance of the solar-driven interfacial evaporation system. We describe the possibilities for applying this efficient solar-driven interfacial evaporation process for energy conversion applications. The exciting opportunities and challenges in both fundamental research and practical implementation of the solar-driven interfacial evaporation process are also discussed. The thermal properties of solar energy can be exploited for many applications, including evaporation. Tao et al. review recent developments in the field of solar-driven interfacial evaporation, which have enabled higher-performance structures by localizing energy conversion to the air/liquid interface.
1,139 citations
Authors
Showing all 86514 results
Name | H-index | Papers | Citations |
---|---|---|---|
Yi Chen | 217 | 4342 | 293080 |
H. S. Chen | 179 | 2401 | 178529 |
Zhenan Bao | 169 | 865 | 106571 |
Gang Chen | 167 | 3372 | 149819 |
Peter G. Schultz | 156 | 893 | 89716 |
Xiang Zhang | 154 | 1733 | 117576 |
Rui Zhang | 151 | 2625 | 107917 |
Yi Yang | 143 | 2456 | 92268 |
Markku Kulmala | 142 | 1487 | 85179 |
Jian Yang | 142 | 1818 | 111166 |
Wei Huang | 139 | 2417 | 93522 |
Bin Liu | 138 | 2181 | 87085 |
Jun Lu | 135 | 1526 | 99767 |
Hui Li | 135 | 2982 | 105903 |
Lei Zhang | 135 | 2240 | 99365 |