Institution
United States Department of Energy
Government•Washington D.C., District of Columbia, United States•
About: United States Department of Energy is a government organization based out in Washington D.C., District of Columbia, United States. It is known for research contribution in the topics: Catalysis & Coal. The organization has 13656 authors who have published 14177 publications receiving 556962 citations. The organization is also known as: DOE & Department of Energy.
Topics: Catalysis, Coal, Combustion, Adsorption, Hydrogen
Papers published on a yearly basis
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TL;DR: The Indian National Gas Hydrate Program Expedition 01 (NGHP-01) is designed to study the occurrence of gas hydrate along the passive continental margin of the Indian Peninsula and in the Andaman convergent margin this article.
167 citations
TL;DR: It is found that PtRh nanoparticles with sufficiently high Rh content survive extended calcination at temperatures up to approximately 850 degrees C without significant sintering and should be broadly applicable to the development of multi-metallic nanomaterials for a broad range of high-temperature applications.
Abstract: Metal nanoparticles with precisely controlled size and composition are highly attractive for heterogeneous catalysis. However, their poor thermal stability remains a major hurdle on the way towards application at realistic technical conditions. Recent progress in this area has focused on nanostructured oxides to stabilize embedded metal nanoparticles. Here, we report an alternative approach that relies on synthesizing bimetallic nanoparticles with precise compositional control to obtain improved high-temperature stability. We find that PtRh nanoparticles with sufficiently high Rh content survive extended calcination at temperatures up to approximately 850 degrees C without significant sintering. For lower Rh content, sacrificial self-stabilization of individual nanoparticles through a distillation-like process is observed: the low-melting-point metal (Pt) bleeds out and the increasing concentration of the high-melting-point metal (Rh) leads to re-stabilization of the remaining nanoparticle. This principle of thermal self-stabilization should be broadly applicable to the development of multi-metallic nanomaterials for a broad range of high-temperature applications.
166 citations
TL;DR: In this article, the bulk and surface characteristics during decomposition of the transition metal sulfates of copper, iron (II), iron (III), nickel, and zinc are investigated utilizing various spectroscopic techniques.
166 citations
TL;DR: In this paper, the authors proposed a unified modeling approach for the numerical prediction of dilute and dense gas-solid two-phase flow with appropriate boundary conditions (BC) with a small specularity coefficient or simply the free slip BC.
166 citations
TL;DR: Various cationic species of Hg and Pb are separated as ion pairs by reversed-phase liquid chromatography and lead is detected by inductively coupled plasma mass spectrometry.
Abstract: Various cationic species of Hg (Hg 2+ , MeHg + , EtHg + , and PhHg + ) and Pb 2+ , (Me) 3 Pb + , and (Et) 3 Pb + ) are separated as ion pairs by reversed-phase liquid chromatography. Lead is detected ≃0.2 pg and Hg at ≃7 pg by inductively coupled plasma mass spectrometry. A direct injection nebulizer minimizes band broadening and yields good sensitivity by injecting all the sample into the plasma
166 citations
Authors
Showing all 13660 results
| Name | H-index | Papers | Citations |
|---|---|---|---|
| Martin White | 196 | 2038 | 232387 |
| Paul G. Richardson | 183 | 1533 | 155912 |
| Jie Zhang | 178 | 4857 | 221720 |
| Krzysztof Matyjaszewski | 169 | 1431 | 128585 |
| Yang Gao | 168 | 2047 | 146301 |
| David Eisenberg | 156 | 697 | 112460 |
| Marvin Johnson | 149 | 1827 | 119520 |
| Carlos Escobar | 148 | 1184 | 95346 |
| Joshua A. Frieman | 144 | 609 | 109562 |
| Paul Jackson | 141 | 1372 | 93464 |
| Greg Landsberg | 141 | 1709 | 109814 |
| J. Conway | 140 | 1692 | 105213 |
| Pushpalatha C Bhat | 139 | 1587 | 105044 |
| Julian Borrill | 139 | 387 | 102906 |
| Cecilia Elena Gerber | 138 | 1727 | 106984 |