Institution
United States Department of Energy
Government•Washington D.C., District of Columbia, United States•
About: United States Department of Energy is a government organization based out in Washington D.C., District of Columbia, United States. It is known for research contribution in the topics: Catalysis & Coal. The organization has 13656 authors who have published 14177 publications receiving 556962 citations. The organization is also known as: DOE & Department of Energy.
Topics: Catalysis, Coal, Combustion, Adsorption, Hydrogen
Papers published on a yearly basis
Papers
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Natural Environment Research Council1, European Bioinformatics Institute2, Biotechnology and Biological Sciences Research Council3, Medical Research Council4, United States Department of Energy5, Wellcome Trust Sanger Institute6, Seattle Children's7, Gordon and Betty Moore Foundation8, Economic and Social Research Council9, European Science Foundation10, Wellcome Trust11, Science Commons12
TL;DR: Data sharing, and the good annotation practices it depends on, must become part of the fabric of daily research for researchers and funders.
Abstract: Development of high-throughput genomic and postgenomic technologies has caused a change in approaches to data handling and processing ( 1 ). One biological sample might be used to generate many kinds of “big” data in parallel, such as genome sequence (genomics), patterns of gene and protein expression (transcriptomics and proteomics), and metabolite concentrations and fluxes (metabolomics). Extensive computer manipulations are required for even basic analyses of such data; the challenges mount further when two or more studies' outputs must be compared or integrated.
144 citations
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TL;DR: The US Department of Energy (DOE) has been evaluating the unsaturated zone (UZ) at Yucca Mountain, Nevada, as a potential repository site for high level nuclear waste.
144 citations
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TL;DR: A simple model has been developed that allows extraction of the enantiospecific equilibrium constants for (R)- and (S)-propylene oxide adsorption on the chiral Au nanoparticles.
Abstract: The surfaces of chemically synthesized Au nanoparticles have been modified with d- or l-cysteine to render them chiral and enantioselective for adsorption of chiral molecules. Their enantioselective interaction with chiral compounds has been probed by optical rotation measurements during exposure to enantiomerically pure and racemic propylene oxide. The ability of optical rotation to detect enantiospecific adsorption arises from the fact that the specific rotation of polarized light by (R)- and (S)-propylene oxide is enhanced by interaction with Au nanoparticles. This effect is related to previous observations of enhanced circular dichroism by Au nanoparticles modified by chiral adsorbates. More importantly, chiral Au nanoparticles modified with either d- or l-cysteine selectively adsorb one enantiomer of propylene oxide from a solution of racemic propylene oxide, thus leaving an enantiomeric excess in the solution phase. Au nanoparticles modified with l-cysteine (d-cysteine) selectively adsorb the (R)-pr...
144 citations
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TL;DR: In this article, aluminum-doped zinc oxide (ZnO:Al), one of the promising TCOs, was prepared by radio frequency (RF) magnetron sputtering on glass (Corning 1737) substrates as a function of the deposition condition Argon gas pressure during deposition was kept in the range 004-133 Pa, and the temperature was maintained in between 300 and 673 K.
144 citations
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TL;DR: Three major challenges to the field of chiral surface science are outlined: development of methods for detection of enantiospecific interactions and enantioselective surface chemistry, preparation of high-area chiral metal surfaces, and the development of a fundamental, predictive-level understanding of the origin of enantiOSElectivity on chiral surfaces.
Abstract: Chiral surfaces serve as media for enantioselective chemical processes. Their chirality is dictated by atomic- and molecular-level structure, and their enantioselectivity is determined by their enantiospecific interactions with chiral adsorbates. This Perspective describes three types of chiral metal surfaces: those modified by adsorption of chiral molecules, those templated by chiral lattices of adsorbed species, and those that are naturally chiral. A new paper in this issue of ACS Nano offers insight into the intermolecular interactions that govern chiral templating of surfaces. This Perspective then outlines three major challenges to the field of chiral surface science: development of methods for detection of enantiospecific interactions and enantioselective surface chemistry, preparation of high-area chiral metal surfaces, and the development of a fundamental, predictive-level understanding of the origin of enantioselectivity on chiral surfaces.
144 citations
Authors
Showing all 13660 results
Name | H-index | Papers | Citations |
---|---|---|---|
Martin White | 196 | 2038 | 232387 |
Paul G. Richardson | 183 | 1533 | 155912 |
Jie Zhang | 178 | 4857 | 221720 |
Krzysztof Matyjaszewski | 169 | 1431 | 128585 |
Yang Gao | 168 | 2047 | 146301 |
David Eisenberg | 156 | 697 | 112460 |
Marvin Johnson | 149 | 1827 | 119520 |
Carlos Escobar | 148 | 1184 | 95346 |
Joshua A. Frieman | 144 | 609 | 109562 |
Paul Jackson | 141 | 1372 | 93464 |
Greg Landsberg | 141 | 1709 | 109814 |
J. Conway | 140 | 1692 | 105213 |
Pushpalatha C Bhat | 139 | 1587 | 105044 |
Julian Borrill | 139 | 387 | 102906 |
Cecilia Elena Gerber | 138 | 1727 | 106984 |