Institution
Nanjing Tech University
Education•Nanjing, China•
About: Nanjing Tech University is a education organization based out in Nanjing, China. It is known for research contribution in the topics: Catalysis & Membrane. The organization has 21827 authors who have published 21794 publications receiving 364050 citations. The organization is also known as: Nangongda & Nánjīng Gōngyè Dàxúe.
Topics: Catalysis, Membrane, Adsorption, Chemistry, Microstructure
Papers published on a yearly basis
Papers
More filters
••
TL;DR: The mesoporous and hollow structure enhance the gas sensitivity of ZnO microsphere, and the obtained Zn O microspheres based sensor has an excellent performance for precision detection of ethanol and acetone with low concentration.
Abstract: Mesoporous and hollow structure have been attracting increasing attention for their special properties and potential applications. Here we show a facile fabrication of hollow and mesoporous ZnO microsphere via a one-step wet chemical process using polyethylene glycol (PEG, MW 200) as the solvent and soft template. The morphology and structure of the products were characterized by using scanning electron microscopy and X-ray powder diffraction techniques. Thermal analysis and Fourier transform infrared spectroscopy techniques were also performed to show the properties of the precursor and annealed product. A possible growth mechanism of hollow and mesoporous ZnO microsphere was also proposed. The Brunauer–Emmett–Teller surface area of ZnO microsphere is 28.5 m2g–1 and the size of mesopores is about 10 nm. The Photoluminescence spectra of the as-synthesized ZnO hollow microspheres were also presented. The mesoporous and hollow structure enhance the gas sensitivity of ZnO microsphere, and the obtained ZnO mi...
103 citations
••
TL;DR: In this article, a visible-light-driven nitrogen-doped TiO2 was synthesized using a novel nitrogen-ion donor of hydrazine hydrate, which showed higher photocatalytic activity for degradation of 4-chlorophenol (4-CP) under visible irradiation (λ>400 nm).
103 citations
••
TL;DR: The results showed that the reaction of nano-SiO2 particles with Ca(OH)2 (crystal powder) started within 1 h, and formed C–S–H gel, which was faster after aging for three days, and the early strength enhancement of test pieces was obvious.
Abstract: This paper systematically studied the modification of cement-based materials by nano-SiO2 particles with an average diameter of about 20 nm. In order to obtain the effect of nano-SiO2 particles on the mechanical properties, hydration, and pore structure of cement-based materials, adding 1%, 3%, and 5% content of nano-SiO2 in cement paste, respectively. The results showed that the reaction of nano-SiO2 particles with Ca(OH)2 (crystal powder) started within 1 h, and formed C–S–H gel. The reaction speed was faster after aging for three days. The mechanical properties of cement-based materials were improved with the addition of 3% nano-SiO2, and the early strength enhancement of test pieces was obvious. Three-day compressive strength increased 33.2%, and 28-day compressive strength increased 18.5%. The exothermic peak of hydration heat of cement increased significantly after the addition of nano-SiO2. Appearance time of the exothermic peak was advanced and the total heat release increased. Thermogravimetric-differential scanning calorimetry (TG-DSC) analysis showed that nano-SiO2 promoted the formation of C–S–H gel. The results of mercury intrusion porosimetry (MIP) showed that the total porosity of cement paste with 3% nano-SiO2 was reduced by 5.51% and 5.4% at three days and 28 days, respectively, compared with the pure cement paste. At the same time, the pore structure of cement paste was optimized, and much-detrimental pores and detrimental pores decreased, while less harmful pores and innocuous pores increased.
103 citations
••
TL;DR: Pervaporation is a molecular separation membrane technology for selective permeation of water or organic compounds from organic-water mixtures or organic-organic mixtures as mentioned in this paper, which is controlled by thermodynamic partitioning and kinetic mobility of molecules in the membrane.
103 citations
••
TL;DR: The introduction of four MOPs (constructed from dicopper and carboxylates) to cavity-structured mesoporous silica SBA-16 via a double-solvent strategy to overcome both shortcomings simultaneously and the structure and catalytic activity of Mops in confined cavities are well preserved after exposure to humid atmosphere, whereas those of bulk MOP
Abstract: Metal-organic polyhedra (MOPs) have attracted great attention due to their intriguing structure. However, the applications of MOPs are severely hindered by two shortcomings, namely low dispersity and poor stability. Here we report the introduction of four MOPs (constructed from dicopper and carboxylates) to cavity-structured mesoporous silica SBA-16 via a double-solvent strategy to overcome both shortcomings simultaneously. By judicious design, the dimension of MOPs is just between the size of cavities and entrances of SBA-16, MOP molecules are thus confined in the cavities. This leads to the formation of isolated MOPs with unusual dispersion, making the active sites highly accessible. Hence, the adsorption capacity on carbon dioxide and propene as well as catalytic performance on ring opening are much superior to bulk MOPs. More importantly, the structure and catalytic activity of MOPs in confined cavities are well preserved after exposure to humid atmosphere, whereas those of bulk MOPs are degraded seriously.
103 citations
Authors
Showing all 22047 results
Name | H-index | Papers | Citations |
---|---|---|---|
Yi Chen | 217 | 4342 | 293080 |
Richard H. Friend | 169 | 1182 | 140032 |
Hua Zhang | 163 | 1503 | 116769 |
Wei Huang | 139 | 2417 | 93522 |
Jian Zhou | 128 | 3007 | 91402 |
Haiyan Wang | 119 | 1674 | 86091 |
Jian Liu | 117 | 2090 | 73156 |
Lain-Jong Li | 113 | 627 | 58035 |
Hong Wang | 110 | 1633 | 51811 |
Jun-Jie Zhu | 103 | 754 | 41655 |
Stefan Kaskel | 101 | 705 | 36201 |
Hong Liu | 100 | 1905 | 57561 |
Dirk De Vos | 96 | 642 | 33214 |
Peng Li | 95 | 1548 | 45198 |
Feng Liu | 95 | 1067 | 38478 |