Journal ArticleDOI
.alpha.-Methoxy-.alpha.-trifluoromethylphenylacetic acid, a versatile reagent for the determination of enantiomeric composition of alcohols and amines
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This article is published in Journal of Organic Chemistry.The article was published on 1969-09-01. It has received 2312 citations till now. The article focuses on the topics: Reagent.read more
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Asymmetric epoxidation of allylic alcohol by the modified Sharpless reagent
Zhi-Min Wang,Wei-Shan Zhou +1 more
TL;DR: The modified Sharpless reagent can be applied to the epoxidation of various allylic alcohols just as the Sharpless Reagent does, but the reaction time was greatly reduced as discussed by the authors.
Journal ArticleDOI
Synthese enantiospecifique du 5-hexadecanolide, pheromone de “Vespa Orientalis”
M. Larcheveque,Julien Lalande +1 more
TL;DR: In this article, a synthetic scheme was elaborated to prepare δ-n-hexa-decanolactone 10 in 8 steps from (L)-glutamic acid.
Journal ArticleDOI
Synthesis of optically active 2-furylmethanols as useful chiral building blocks and its application to the synthesis of (5R,6S)-6-acetoxyhexadecan-5-olide and (+)-disparlure
TL;DR: In this article, a racemic secondary 2-furylmethanols (S)-1-(2-Furyl)undecanol (1f) was used as a chiral building block in the synthesis of (5R,6S)-6-acetoxyhexadecan-5-olide and (+)-disparlure.
Journal ArticleDOI
Broadening in the scope of NADH models by using chiral and non chiral pyrrolo [2,3-bl pyridine derivatives.
TL;DR: Non cliral and chiral NADH models in the pyrrolo [2,3-b] pyridine series have been synthesized and can be used in the synthesis of chiral precursors of target molecules obtained with good enantiomeric excesses.
Journal ArticleDOI
Applications of MTPA (Mosher) Amides of Secondary Amines: Assignment of Absolute Configuration in Chiral Cyclic Amines
Thomas R. Hoye,Matthew K. Renner +1 more
TL;DR: In this article, Mosher's MTPA technology is applied to the assignment of absolute configuration of several synthetic and natural chiral amines, and two complementary sets of Δδ values are obtained from a single analysis, thereby enhancing the power of the method.
Related Papers (5)
Nuclear magnetic resonance enantiomer regents. Configurational correlations via nuclear magnetic resonance chemical shifts of diastereomeric mandelate, O-methylmandelate, and .alpha.-methoxy-.alpha.-trifluoromethylphenylacetate (MTPA) esters
James A. Dale,Harry S. Mosher +1 more