Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules.
Kang Liang,Raffaele Ricco,Cara M. Doherty,Mark J. Styles,Stephen Bell,Nigel Kirby,Stephen T. Mudie,David N. Haylock,Anita J. Hill,Christian J. Doonan,Paolo Falcaro +10 more
TLDR
It is shown that proteins, enzymes and DNA rapidly induce the formation of protective metal-organic framework coatings under physiological conditions by concentrating the framework building blocks and facilitating crystallization around the biomacromolecules.Abstract:
Robust biomacromolecules could be used for a wide range of biotechnological applications. Here the authors report a biomimetic mineralization process, in which biomolecules are encapsulated within metal-organic frameworks, and their stability is subsequently increased without significant bioactivity loss.read more
Citations
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Journal Article
Methods in Enzymology.
TL;DR: This volume is keyed to high resolution electron microscopy, which is a sophisticated form of structural analysis, but really morphology in a modern guise, the physical and mechanical background of the instrument and its ancillary tools are simply and well presented.
Journal ArticleDOI
Metal-Organic Frameworks as Platforms for Catalytic Applications.
TL;DR: An overview of recent developments achieved in MOF catalysis, including heterogeneousCatalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided.
Journal ArticleDOI
Enzyme–MOF (metal–organic framework) composites
Xizhen Lian,Yu Fang,Elizabeth A. Joseph,Qi Wang,Jialuo Li,Sayan Banerjee,Christina T. Lollar,Xuan Wang,Hong-Cai Zhou +8 more
TL;DR: This review summarizes recent developments of MOF-enzyme composites with special emphasis on preparative techniques and the synergistic effects of enzymes and MOFs.
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From fundamentals to applications: a toolbox for robust and multifunctional MOF materials.
TL;DR: This review provides insight into both existing structures and emerging aspects of MOFs, as well as emerging trends of MOF development.
Journal ArticleDOI
Hybridization of MOFs and polymers
TL;DR: This review article focuses on the methodology for hybridization of MOFs and polymers, as well as the intriguing functions of hybrid materials.
References
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Journal ArticleDOI
Using Functional Nano- and Microparticles for the Preparation of Metal–Organic Framework Composites with Novel Properties
TL;DR: This Account summarizes recent progress in the use of nano- and microparticles to control the function, location, and 3D structure of MOFs during MOF self-assembly, creating novel, hybrid, multifunctional, ultraporous materials as a first step towards creating MOF-based devices.
Journal ArticleDOI
A new method to position and functionalize metal-organic framework crystals
Paolo Falcaro,Anita J. Hill,Kate M. Nairn,Jacek J. Jasieniak,James I. Mardel,Timothy J. Bastow,Sheridan C Mayo,Michele Gimona,Daniel E. Gómez,H.J. Whitfield,Raffaele Ricco,Alessandro Patelli,Benedetta Marmiroli,Heinz Amenitsch,T.A. Colson,Laura Villanova,Dario Buso,Dario Buso +17 more
TL;DR: Affording spatial control of nucleation and significantly accelerating MOF growth, these α-hopeite microparticles are found to act as nucleation agents both in solution and on solid surfaces and translates directly to the fabrication of functional MOFs suitable for molecular size-selective applications.
Book ChapterDOI
From Fundamentals to Applications
TL;DR: Fluoropolymer is a polymer consisting of carbon (C) and fluorine (F), sometimes referred to as perfluorpolymers to distinguish them from partially fluorinated polymers, fluoroelastomers, and other polymers that contain fluorine in their chemical structure.
Journal ArticleDOI
Fast Nucleation and Growth of ZIF‐8 Nanocrystals Monitored by Time‐Resolved In Situ Small‐Angle and Wide‐Angle X‐Ray Scattering
Janosch Cravillon,Christian A. Schröder,Roman Nayuk,Jérémie Gummel,Klaus Huber,Michael Wiebcke +5 more
TL;DR: The complex crystallization process exhibits similarities with crystallization processes of zeolites from solution with nano-sized clusters during the nucleation and early growth of nanocrystals of a zeolitic imidazolate framework (ZIF).
Journal ArticleDOI
Structural and luminescent properties of micro- and nanosized particles of lanthanide terephthalate coordination polymers.
Carole Daiguebonne,Nicolas Kerbellec,Olivier Guillou,Jean-Claude G. Bünzli,Frédéric Gumy,Laure Catala,Talal Mallah,Nathalie Audebrand,Yves Gérault,Kevin Bernot,Guillaume Calvez +10 more
TL;DR: The isostructurality of the compounds with the previously reported Tb-containing polymer is ascertained on the basis of their X-ray powder diffraction diagrams and the luminescence properties of all the compounds have been recorded and the two most luminescent polymers have been studied in more detail.