Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules.
Kang Liang,Raffaele Ricco,Cara M. Doherty,Mark J. Styles,Stephen Bell,Nigel Kirby,Stephen T. Mudie,David N. Haylock,Anita J. Hill,Christian J. Doonan,Paolo Falcaro +10 more
TLDR
It is shown that proteins, enzymes and DNA rapidly induce the formation of protective metal-organic framework coatings under physiological conditions by concentrating the framework building blocks and facilitating crystallization around the biomacromolecules.Abstract:
Robust biomacromolecules could be used for a wide range of biotechnological applications. Here the authors report a biomimetic mineralization process, in which biomolecules are encapsulated within metal-organic frameworks, and their stability is subsequently increased without significant bioactivity loss.read more
Citations
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Multifunctional Cathodic Interlayer with Polysulfide Immobilization Mechanism for High-Performance Li-S Batteries
Muhammad Waqas,Afaque Manzoor Soomro,Afaque Manzoor Soomro,Shamshad Ali,Suresh Kumar,Sattar Chan,Kashif Hussain,Kashif Hussain,Fida Hussain Memon,Shoaib Ahmed Shaikh +9 more
Journal ArticleDOI
One-pot synthesis of trypsin-based magnetic metal–organic frameworks for highly efficient proteolysis
TL;DR: A facile approach for the one-pot synthesis of trypsin-immobilized magnetic zeolite imidazolate framework-8 (iron oxide@ZIF-8@trypsin) is reported, which could be applied as an immobilized enzyme microreactor (IMER) to rapidly and efficiently digest proteins and complex human serum samples with satisfactory results, showing great promise for application in proteomic analysis.
Journal ArticleDOI
Lead–Organic Frameworks Containing Trimesic Acid: Facile Dissolution–Crystallization and Near-White Light Emission
Mesoun A. A. Al-Nubi,Aliyu M. Hamisu,Fendi Y. Wardana,Azhar Ariffin,Hongil Jo,Kang Min Ok,Arief Wibowo +6 more
TL;DR: In this article, three Pb-based organic frameworks were synthesized using a simple and optimized dissolution-crystallization method with benzene-1,3,5-tricarboxylic acid (H3BTC).
Journal ArticleDOI
Nanotechnologies for Intracellular Protein Delivery: Recent Progress in Inorganic and Organic Nanocarriers
Sarah Le Saux,Anne Aubert-Pouëssel,Lyria Ouchait,Khaled Elhady Mohamed,Pierre Martineau,Laurence Guglielmi,Jean-Marie Devoisselle,Philippe Legrand,Joël Chopineau,Marie Morille +9 more
TL;DR: The authors describe the most recent progress in the development of inorganic (silica, gold, phosphate, metal–organic framework, carbon nanoparticles) as well as organic (polymer, lipid) nanoparticles, both applied to intracellular protein delivery.
Journal ArticleDOI
Biomimetic core-shell silica nanoparticles using a dual-functional peptide.
TL;DR: The fundamental mechanism of silica formation through a peptide catalyzed biosilicification was systematically investigated, so that the formation of oil-core silica-shell nanocapsules can be precisely controlled.
References
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The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
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Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.
Book ChapterDOI
The assay of catalases and peroxidases.
Britton Chance,A.C. Maehly +1 more
TL;DR: Two methods are described for the catalase assay by disappearance of peroxide are: ultraviolet spectrophotometry and permanganate titration and indirect measurements of the decrease of light absorption caused by the decomposition of hydrogen peroxide byCatalase.
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Metal-organic frameworks in biomedicine.
Patricia Horcajada,Ruxandra Gref,Tarek Baati,Phoebe K. Allan,Guillaume Maurin,Patrick Couvreur,Gérard Férey,Russell E. Morris,Christian Serre +8 more
TL;DR: Metal Organic Frameworks in Biomedicine Patricia Horcajada, Ruxandra Gref, Tarek Baati, Phoebe K. Allan, Guillaume Maurin, Patrick Couvreur, G erard F erey, Russell E. Morris, and Christian Serre.