Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules.
Kang Liang,Raffaele Ricco,Cara M. Doherty,Mark J. Styles,Stephen Bell,Nigel Kirby,Stephen T. Mudie,David N. Haylock,Anita J. Hill,Christian J. Doonan,Paolo Falcaro +10 more
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TLDR
It is shown that proteins, enzymes and DNA rapidly induce the formation of protective metal-organic framework coatings under physiological conditions by concentrating the framework building blocks and facilitating crystallization around the biomacromolecules.Abstract:
Robust biomacromolecules could be used for a wide range of biotechnological applications. Here the authors report a biomimetic mineralization process, in which biomolecules are encapsulated within metal-organic frameworks, and their stability is subsequently increased without significant bioactivity loss.read more
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De Novo Approach to Encapsulating Biocatalysts into Synthetic Matrixes: From Enzymes to Microbial Electrocatalysts.
TL;DR: In this paper, the authors summarize the emerging de novo approaches to encapsulating biocatalysts into synthetic matrixes and highlight the benefit of encapsulation in facilitating the transport of charge carriers in microbial electrocatalysis.
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Hydrogen-Bonded Organic Frameworks (HOFs)-Based Single-Neural Stem Cell Encapsulation and Transplantation to Remodel Impaired Neural Networks.
TL;DR: A new way to encapsulation of NSC by using hydrogen-bonded organic frameworks (HOFs) to overcome the common causes of low therapeutic efficacy during NSC transplantation and may inspire design of HOFs-based exoskeleton to ameliorate neurogenesis and cognitive behavioral symptoms associated with AD.
Journal ArticleDOI
Controlled transdermal release of antioxidant ferulate by a porous Sc(III) MOF
Génesis Osorio-Toribio,Miriam de J. Velásquez-Hernández,Paulo G. M. Mileo,J. Antonio Zárate,J. Antonio Zárate,Javier Aguila-Rosas,Javier Aguila-Rosas,Gerardo Leyva-Gómez,Roberto Sánchez-Sánchez,Jonathan J. Magaña,Mario Alberto Pérez-Díaz,Isabel Abánades Lázaro,Isabel Abánades Lázaro,Ross S. Forgan,Guillaume Maurin,Enrique Lima,Ilich A. Ibarra +16 more
TL;DR: The Sc(III) MOF-type MFM-300(Sc) is demonstrated to be stable under physiological conditions, biocompatible, and an efficient drug carrier for the long-term controlled release through human skin of antioxidant ferulate.
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Electron Transfer-Driven Single and Multi-Enzyme BioFuel Cells for Self-Powering and Energybioscience
TL;DR: In this paper , the authors have discussed how energy generation pathways depend on parameters such as current density, electron transport mechanism, and enzyme conformation, and emphasized how EBFC contributes to self-powering of modern biosensors.
Journal ArticleDOI
Polyamide thin-film nanocomposite membrane containing star-shaped ZIF-8 with enhanced water permeance and PPCPs removal
TL;DR: In this paper , the 3D architecture of nanomaterials were used to manipulate the performance of polyamide (PA) thin-film nanocomposite (TFN) membrane.
References
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The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
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Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.
Book ChapterDOI
The assay of catalases and peroxidases.
Britton Chance,A.C. Maehly +1 more
TL;DR: Two methods are described for the catalase assay by disappearance of peroxide are: ultraviolet spectrophotometry and permanganate titration and indirect measurements of the decrease of light absorption caused by the decomposition of hydrogen peroxide byCatalase.
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Metal-organic frameworks in biomedicine.
Patricia Horcajada,Ruxandra Gref,Tarek Baati,Phoebe K. Allan,Guillaume Maurin,Patrick Couvreur,Gérard Férey,Russell E. Morris,Christian Serre +8 more
TL;DR: Metal Organic Frameworks in Biomedicine Patricia Horcajada, Ruxandra Gref, Tarek Baati, Phoebe K. Allan, Guillaume Maurin, Patrick Couvreur, G erard F erey, Russell E. Morris, and Christian Serre.