Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules.
Kang Liang,Raffaele Ricco,Cara M. Doherty,Mark J. Styles,Stephen Bell,Nigel Kirby,Stephen T. Mudie,David N. Haylock,Anita J. Hill,Christian J. Doonan,Paolo Falcaro +10 more
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TLDR
It is shown that proteins, enzymes and DNA rapidly induce the formation of protective metal-organic framework coatings under physiological conditions by concentrating the framework building blocks and facilitating crystallization around the biomacromolecules.Abstract:
Robust biomacromolecules could be used for a wide range of biotechnological applications. Here the authors report a biomimetic mineralization process, in which biomolecules are encapsulated within metal-organic frameworks, and their stability is subsequently increased without significant bioactivity loss.read more
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Activatable Core-Shell Metallofullerene: An Efficient Nanoplatform for Bimodal Sensing of Glutathione.
TL;DR: This work demonstrates feasibility of using fullerenes to fabricate activatable probes for molecular imaging of GSH, which may promote the development of new fullerene-based stimuli-responsive multimodal probes for the detection and regulation of particular biological processes in vivo.
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Selective edge etching to improve the rate capability of Prussian blue analogues for sodium ion batteries
Youhuan Zhu,Bingxue Wang,Qingmeng Gan,Yanfang Wang,Zhengyu Wang,Jiwei Xie,Shuai Gu,Zhiqiang Li,Yingzhi Li,Zong-Wei Ji,Hua Cheng,Zhouguang Lu +11 more
TL;DR: In this paper, a selective edge-etching approach was developed to tackle the long-standing issue of poor rate capability for PBA batteries, where well-crystallized PBA particles were produced by hydrothermal treatment of a sodium hexacyanoferrate precursor dissolved in muriatic acid solution, which were then eroded in hydrochloric acid solution to promote selective etching along the edges of the PBA crystals.
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Enhanced Cancer Starvation Therapy Enabled by an Autophagy Inhibitors-Encapsulated Biomimetic ZIF-8 Nanodrug: Disrupting and Harnessing Dual Pro-Survival Autophagic Responses.
Fenglan Li,Tao Chen,Fang Wang,Jinfa Chen,Yuanyuan Zhang,Danting Song,Ning Li,Xinpei Lin,Lisen Lin,Junyang Zhuang +9 more
TL;DR: In vitro and in vivo results have confirmed the enhanced anticancer effect achieved by mCG@ZIF with a negligible side effect, and a novel nanodrug system, cell membranes-coated zeolitic imidazolate framework-8 (ZIF-8) NPs encapsulating chloroquine (CQ) and glucose oxidase (GOx) (defined as mCG @ZIF), is designed to achieve an enhanced anticancers effect.
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Polymer in MOF Nanospace: from Controlled Chain Assembly to New Functional Materials
Benjamin Le Ouay,Takashi Uemura +1 more
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In Vivo Sampling: A Promising Technique for Detecting and Profiling Endogenous Substances in Living Systems.
TL;DR: The up-to-date progress in the development of microdialysis and solid-phase microextraction are summarized as valuable tools for in vivo sampling of endogenous substances in food and agriculture chemistry.
References
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Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
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Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
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The assay of catalases and peroxidases.
Britton Chance,A.C. Maehly +1 more
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Metal-organic frameworks in biomedicine.
Patricia Horcajada,Ruxandra Gref,Tarek Baati,Phoebe K. Allan,Guillaume Maurin,Patrick Couvreur,Gérard Férey,Russell E. Morris,Christian Serre +8 more
TL;DR: Metal Organic Frameworks in Biomedicine Patricia Horcajada, Ruxandra Gref, Tarek Baati, Phoebe K. Allan, Guillaume Maurin, Patrick Couvreur, G erard F erey, Russell E. Morris, and Christian Serre.