Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules.
Kang Liang,Raffaele Ricco,Cara M. Doherty,Mark J. Styles,Stephen Bell,Nigel Kirby,Stephen T. Mudie,David N. Haylock,Anita J. Hill,Christian J. Doonan,Paolo Falcaro +10 more
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TLDR
It is shown that proteins, enzymes and DNA rapidly induce the formation of protective metal-organic framework coatings under physiological conditions by concentrating the framework building blocks and facilitating crystallization around the biomacromolecules.Abstract:
Robust biomacromolecules could be used for a wide range of biotechnological applications. Here the authors report a biomimetic mineralization process, in which biomolecules are encapsulated within metal-organic frameworks, and their stability is subsequently increased without significant bioactivity loss.read more
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The Current Status of MOF and COF Applications
Ralph Freund,Orysia Zaremba,Giel Arnauts,Rob Ameloot,Grigorii Skorupskii,Mircea Dincă,Anastasiya Bavykina,Jorge Gascon,Aleksander Ejsmont,Joanna Gościańska,Markus Kalmutzki,Ulrich Lächelt,Evelyn Ploetz,Christian Diercks,Stefan Wuttke +14 more
TL;DR: The amalgamation of different disciplines is at the heart of reticular chemistry and has broadened the boundaries of chemistry by opening up an infinite space of chemical composition, structure, and material properties.
Journal ArticleDOI
Metal–organic frameworks: a novel host platform for enzymatic catalysis and detection
Effrosyni Gkaniatsou,Clémence Sicard,Rémy Ricoux,Jean-Pierre Mahy,Nathalie Steunou,Christian Serre,Christian Serre +6 more
TL;DR: The use of metal-organic frameworks (MOFs) as immobilization matrices for enzymes as a platform for emerging applications is reported in this paper, where an overview of strategies developed to prepare enzyme-MOF biocomposites is presented.
Journal ArticleDOI
Metal-organic frameworks as novel matrices for efficient enzyme immobilization: An update review
TL;DR: Recently, metal-organic frameworks have attracted remarkable research interests as novel supporting matrices for efficient enzyme immobilization and protection as discussed by the authors, which is an efficient strategy for enhancing their catalytic performance in continuous industrial practices.
Journal ArticleDOI
Recent Advances in Stretchable and Transparent Electronic Materials
TL;DR: In this article, the key research efforts toward the development of compliant conductors including transparent conductors are surveyed for application in flexible and highly stretchable electronic and electromechanical devices.
Journal ArticleDOI
Hierarchically Engineered Mesoporous Metal-Organic Frameworks toward Cell-free Immobilized Enzyme Systems
Peng Li,Qishui Chen,Timothy C. Wang,Nicolaas A. Vermeulen,B. Layla Mehdi,B. Layla Mehdi,Alice Dohnalkova,Nigel D. Browning,Nigel D. Browning,Dengke Shen,Ryther Anderson,Diego A. Gómez-Gualdrón,Furkan M. Cetin,Jacek Jagiello,Abdullah M. Asiri,J. Fraser Stoddart,Omar K. Farha,Omar K. Farha +17 more
TL;DR: Remarkably, LDH immobilized in the large pores of the MOF is accessible to nicotinamide adenine dinucleotide coenzymes (NAD and NADH), allowing for in situ coenzyme regeneration leading to higher activity than that of the free enzyme.
References
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Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.
Book ChapterDOI
The assay of catalases and peroxidases.
Britton Chance,A.C. Maehly +1 more
TL;DR: Two methods are described for the catalase assay by disappearance of peroxide are: ultraviolet spectrophotometry and permanganate titration and indirect measurements of the decrease of light absorption caused by the decomposition of hydrogen peroxide byCatalase.
Journal ArticleDOI
Metal-organic frameworks in biomedicine.
Patricia Horcajada,Ruxandra Gref,Tarek Baati,Phoebe K. Allan,Guillaume Maurin,Patrick Couvreur,Gérard Férey,Russell E. Morris,Christian Serre +8 more
TL;DR: Metal Organic Frameworks in Biomedicine Patricia Horcajada, Ruxandra Gref, Tarek Baati, Phoebe K. Allan, Guillaume Maurin, Patrick Couvreur, G erard F erey, Russell E. Morris, and Christian Serre.