Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules.
Kang Liang,Raffaele Ricco,Cara M. Doherty,Mark J. Styles,Stephen Bell,Nigel Kirby,Stephen T. Mudie,David N. Haylock,Anita J. Hill,Christian J. Doonan,Paolo Falcaro +10 more
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TLDR
It is shown that proteins, enzymes and DNA rapidly induce the formation of protective metal-organic framework coatings under physiological conditions by concentrating the framework building blocks and facilitating crystallization around the biomacromolecules.Abstract:
Robust biomacromolecules could be used for a wide range of biotechnological applications. Here the authors report a biomimetic mineralization process, in which biomolecules are encapsulated within metal-organic frameworks, and their stability is subsequently increased without significant bioactivity loss.read more
Citations
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Rational Design of Mimic Multienzyme Systems in Hierarchically Porous Biomimetic Metal–Organic Frameworks
TL;DR: The mimic multienzyme systems were used for the efficient colorimetric detection of a series of biomolecules, including glucose and uric acid, and displays the great potential to construct highly functional biocatalysts by integrating the merits of both natural enzymes and MOF mimics.
Journal ArticleDOI
ZIF-8 Degrades in Cell Media, Serum, and Some-But Not All-Common Laboratory Buffers.
Michael A. Luzuriaga,Candace E. Benjamin,Michael W Gaertner,Hamilton Lee,Fabian C. Herbert,Snipta Mallick,Jeremiah J. Gassensmith +6 more
TL;DR: The results show that Zif-8 undergoes surface chemistry changes that may affect the interpretation of cellular uptake and cargo release data, and provides a rational explanation as to how ZIF-8 neatly dissolves in vivo.
Journal ArticleDOI
Metal–organic frameworks for chemical sensing devices
Joseph F. Olorunyomi,Joseph F. Olorunyomi,Shu Teng Geh,Shu Teng Geh,Rachel A. Caruso,Cara M. Doherty +5 more
TL;DR: In this paper, a review examines studies since 2015 that focus on the applications of metal-organic frameworks and devices in chemical sensing, including solid-state sensing applications, based on electronic, electrochemical, electromechanical and optical sensing methods.
Journal ArticleDOI
Metal-organic framework-based nanomaterials for biomedical applications
TL;DR: This review highlights the up-to-date progress of nMOFs related to their bio-applications such as drug delivery, bioimaging, biosensing and biocatalysis.
Journal ArticleDOI
Metal–organic framework nanoparticles for magnetic resonance imaging
TL;DR: A review of the state-of-the-art of metal-organic framework (MOF) nanoparticles and their use in magnetic resonance imaging (MRI) can be found in this article.
References
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Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.
Book ChapterDOI
The assay of catalases and peroxidases.
Britton Chance,A.C. Maehly +1 more
TL;DR: Two methods are described for the catalase assay by disappearance of peroxide are: ultraviolet spectrophotometry and permanganate titration and indirect measurements of the decrease of light absorption caused by the decomposition of hydrogen peroxide byCatalase.
Journal ArticleDOI
Metal-organic frameworks in biomedicine.
Patricia Horcajada,Ruxandra Gref,Tarek Baati,Phoebe K. Allan,Guillaume Maurin,Patrick Couvreur,Gérard Férey,Russell E. Morris,Christian Serre +8 more
TL;DR: Metal Organic Frameworks in Biomedicine Patricia Horcajada, Ruxandra Gref, Tarek Baati, Phoebe K. Allan, Guillaume Maurin, Patrick Couvreur, G erard F erey, Russell E. Morris, and Christian Serre.