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Atomically thin MoS2: a new direct-gap semiconductor

TLDR
The electronic properties of ultrathin crystals of molybdenum disulfide consisting of N=1,2,…,6 S-Mo-S monolayers have been investigated by optical spectroscopy and the effect of quantum confinement on the material's electronic structure is traced.
Abstract
The electronic properties of ultrathin crystals of molybdenum disulfide consisting of N=1,2,…,6 S-Mo-S monolayers have been investigated by optical spectroscopy Through characterization by absorption, photoluminescence, and photoconductivity spectroscopy, we trace the effect of quantum confinement on the material's electronic structure With decreasing thickness, the indirect band gap, which lies below the direct gap in the bulk material, shifts upwards in energy by more than 06 eV This leads to a crossover to a direct-gap material in the limit of the single monolayer Unlike the bulk material, the MoS₂ monolayer emits light strongly The freestanding monolayer exhibits an increase in luminescence quantum efficiency by more than a factor of 10⁴ compared with the bulk material

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Electronic transport and device prospects of monolayer molybdenum disulphide grown by chemical vapour deposition

TL;DR: The electronic transport and device properties of monolayer molybdenum disulphide grown by chemical vapour deposition are reported and it is revealed that these devices have the potential to suppress short channel effects and have high critical breakdown electric field.
Journal ArticleDOI

Solution-Processed Two-Dimensional Metal Dichalcogenide-Based Nanomaterials for Energy Storage and Conversion.

TL;DR: The recent advances of solution-processed 2D MDCs and their hybrid nanomaterials for energy storage and conversion applications, including rechargeable batteries, supercapacitors, electrocatalytic hydrogen generation and solar cells are summarized.
Journal ArticleDOI

Phosphorene: Synthesis, Scale-Up, and Quantitative Optical Spectroscopy.

TL;DR: In this article, a large-scale production of monolayer, bilayer, and few-layer flakes of 2D black phosphorus has been demonstrated at the 10 g scale.
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Metal-Ion-Modified Black Phosphorus with Enhanced Stability and Transistor Performance.

TL;DR: The use of metal-ion modification to enhance both the stability and transistor performance of BP sheets is described and the strategy can be extended to other metal ions such as Fe3+ , Mg2+ , and Hg2- .
References
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Journal ArticleDOI

Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

TL;DR: Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
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Two-dimensional atomic crystals

TL;DR: By using micromechanical cleavage, a variety of 2D crystals including single layers of boron nitride, graphite, several dichalcogenides, and complex oxides are prepared and studied.
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Emerging Photoluminescence in Monolayer MoS2

TL;DR: This observation shows that quantum confinement in layered d-electron materials like MoS(2), a prototypical metal dichalcogenide, provides new opportunities for engineering the electronic structure of matter at the nanoscale.
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Anomalous lattice vibrations of single- and few-layer MoS2.

TL;DR: This work exemplifies the evolution of structural parameters in layered materials in changing from the three-dimensional to the two-dimensional regime by characterized by Raman spectroscopy.
Journal ArticleDOI

The transition metal dichalcogenides discussion and interpretation of the observed optical, electrical and structural properties

J.A. Wilson, +1 more
- 01 May 1969 - 
TL;DR: The transition metal dichalcogenides are about 60 in number as discussed by the authors, and two-thirds of these assume layer structures and can be cleaved down to less than 1000 A and are then transparent in the region of direct band-to-band transitions.
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