Tokyo Institute of Technology

About: Tokyo Institute of Technology is a education organization based out in Tokyo, Tôkyô, Japan. It is known for research contribution in the topics: Catalysis & Thin film. The organization has 46775 authors who have published 101656 publications receiving 2357893 citations. The organization is also known as: Tokyo Tech & Tokodai.

Nature-Inspired, Highly Durable CO2 Reduction System Consisting of a Binuclear Ruthenium(II) Complex and an Organic Semiconductor Using Visible Light.

Abstract: A metal-free organic semiconductor of mesoporous graphitic carbon nitride (C3N4) coupled with a Ru(II) binuclear complex (RuRu′) containing photosensitizer and catalytic units selectively reduced CO2 into HCOOH under visible light (λ > 400 nm) in the presence of a suitable electron donor with high durability, even in aqueous solution. Modification of C3N4 with Ag nanoparticles resulted in a RuRu′/Ag/C3N4 photocatalyst that exhibited a very high turnover number (>33000 with respect to the amount of RuRu′), while maintaining high selectivity for HCOOH production (87–99%). This turnover number was 30 times greater than that reported previously using C3N4 modified with a mononuclear Ru(II) complex, and by far the highest among the metal-complex/semiconductor hybrid systems reported to date. The results of photocatalytic reactions, emission decay measurements, and time-resolved infrared spectroscopy indicated that Ag nanoparticles on C3N4 collected electrons having lifetimes of several milliseconds from the co...

Stereoselective ring-opening polymerization of a racemic lactide by using achiral salen- and homosalen-aluminum complexes.

Abstract: Highly isotactic polylactide or poly(lactic acid) is synthesized in a ring-opening polymerization (ROP) of racemic lactide with achiral salen- and homosalen-aluminum complexes (salenH(2)=N,N'-bis(salicylidene)ethylene-1,2-diamine; homosalenH(2)=N,N'-bis(salicylidene)trimethylene-1,3-diamine). A systematic exploration of ligands demonstrates the importance of the steric influence of the Schiff base moiety on the degree of isotacticity and the backbone for high activity. The complexes prepared in situ are pure enough to apply to the polymerizations without purification. The crystal structures of the key complexes are elucidated by X-ray diffraction, which confirms that they are chiral. However, analysis of the (1)H and (13)C NMR spectra unambiguously demonstrates that their conformations are so flexible that the chiral environment of the complexes cannot be maintained in solution at 25 degrees C and that the complexes are achiral under the polymerization conditions. The flexibility of the backbone in the propagation steps is also documented. Hence, the isotacticity of the polymer occurs due to a chain-end control mechanism. The highest reactivity in the present system is obtained with the homosalen ligand with 2,2-dimethyl substituents in the backbone (ArCH==NCH(2)CMe(2)CH(2)N==CHAr), whereas tBuMe(2)Si substituents at the 3-positions of the salicylidene moieties lead to the highest selectivity (P(meso)=0.9(8); T(m)=210 degrees C). The ratio of the rate constants in the ROPs of racemic lactide and L-lactide is found to correlate with the stereoselectivity in the present system. The complex can be utilized in bulk polymerization, which is the most attractive in industry, although with some loss of stereoselectivity at high temperature, and the afforded polymer shows a higher melting temperature (P(meso)=0.9(2), T(m) up to 189 degrees C) than that of homochiral poly(L-lactide) (T(m)=162-180 degrees C). The "livingness" of the bulk polymerization at 130 degrees C is maintained even at a high conversion (97-98 %) and for an extended polymerization time (1-2 h).

Multi-parent recombination with simplex crossover in real coded genetic algorithms

Abstract: In this paper, we proposed simplex crossover (SPX), a multi-parent recombination operator for real-coded genetic algorithms. SPX generates offspring vector values by uniformly sampling values from simplex formed by m (2 ≤ m ≤ number of parameters + 1) parent vectors. The SPX features an independence from of coordinate systems. Experimental results using test functions, which are commonly used in studies of evolutionary algorithms, showed SPX works well on functions having multimodality and/or epistasis with a medium number of parents: 3-parent on a low dimensional function or 4 parents on high dimensional functions.

Global UHP metamorphism and continental subduction/collision: The himalayan model

Abstract: Continental crust (density ~2.8 g·cm-3) resists subduction into the earth's mantle (~3.3 g·cm-3) because of buoyancy. However, more than 20 recognized ultrahigh-pressure (UHP) terranes have been documented; these occurrences demonstrate that not only is continental crust subducted to depths as great as 150 km, but also that some supracrustal rocks were then exhumed to the earth's surface. UHP terranes are composed of mainly supracrustal rocks that contain minor amounts of minerals such as coesite or diamond, indicative of P > 2.5 GPa. In general, quartzofeldspathic units are thoroughly back reacted, and only mafic eclogite lenses and boudins retain scattered UHP phases. These index minerals are restricted to micron-scale inclusions in chemically and mechanically resistant zircon, garnet, and a few other strong container minerals, and are difficult to identify by conventional petrologic studies. The continental rocks were subjected to UHP metamorphism at T ranging from ~700 to 950°C and P > 2.8 to 5.0 GPa,...