Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Designing Li-protective layer via SOCl2 additive for stabilizing lithium-sulfur battery
TL;DR: Li et al. as discussed by the authors proposed a facile and effective strategy using thionyl chloride (SOCl2) as electrolyte additive to in-situ build a stable interfacial protective layer on lithium anode to prevent Li dendrite growth.
Journal ArticleDOI
Recent progress in carbon/lithium metal composite anode for safe lithium metal batteries
TL;DR: In this paper, a review summarizes the recent progress in the development of porous nanocarbon materials for safe Li metal anodes and the perspectives regarding the challenges and future development of employing micro-nano-porous carbon materials in Li-metal anodes are also included.
Journal ArticleDOI
Dendrite-Free Lithium Deposition via Flexible-Rigid Coupling Composite Network for LiNi0.5Mn1.5O4/Li Metal Batteries
Jingchao Chai,Bingbing Chen,Fang Xian,Peng Wang,Huiping Du,Jianjun Zhang,Zhihong Liu,Huanrui Zhang,Shanmu Dong,Xinhong Zhou,Guanglei Cui +10 more
TL;DR: A kind of 3D-cross-linked composite network is successfully employed as a flexible-rigid coupling protective layer on a lithium metal electrode, resulting in a dendrite-free deposition at a current density of 2 mA cm-2 .
Journal ArticleDOI
An advance review of solid-state battery: Challenges, progress and prospects
TL;DR: In this paper, a review summarizes the foremost challenges in line with the type of solid electrolyte, provides a comprehensive overview of the advance developments in optimizing the performance of the solid electrolytes, and indicates the direction for the future research direction of solid-state batteries and advancing industrialization.
Journal ArticleDOI
In situ regulated solid electrolyte interphase via reactive separators for highly efficient lithium metal batteries
TL;DR: In this article, a lignosulfonate film with intrinsic reactivity toward Li metal is integrated onto the surface of a routine separator, which contributes to a reduced voltage polarization and a remarkably prolonged cycle life of the working LMBs.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
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Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.