Journal ArticleDOI
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.
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TLDR
This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.Abstract:
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...read more
Citations
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Stable artificial solid electrolyte interphase films for lithium metal anode via metal–organic frameworks cemented by polyvinyl alcohol
Lishuang Fan,Zhikun Guo,Yu Zhang,Xian Wu,Chenyang Zhao,Xun Sun,Guiye Yang,Yujie Feng,Naiqing Zhang +8 more
TL;DR: In this article, a stable artificial solid electrolyte interphase (SEI) film, which was prepared by polyvinyl alcohol (PVA) cementing a metal organic framework (Zn-MOF), was introduced.
Journal ArticleDOI
Rechargeable Aqueous Zinc-Ion Batteries with Mild Electrolytes: A Comprehensive Review
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Electrolyte Confinement Alters Lithium Electrodeposition
TL;DR: In this paper, it was shown that the passivating film formed due to lithium's high reactivity alters the surface energies and in turn deposition preference for fresh lithium, leading to nonuniform surface structure growth and traps the electrolyte layer.
Journal ArticleDOI
A carbon cloth-based lithium composite anode for high-performance lithium metal batteries
Ying Zhou,Yu Han,Hongtao Zhang,Dong Sui,Zhenhe Sun,Peishuang Xiao,Xueting Wang,Yanfeng Ma,Yongsheng Chen +8 more
TL;DR: Li et al. as mentioned in this paper developed a facile method to prepare dendrite-mitigation Li composite electrode (Li@CC) using commercial carbon cloth as the interfacial layer between Li metal anode and the electrolyte.
Journal ArticleDOI
Interfacial engineering for stabilizing polymer electrolytes with 4V cathodes in lithium metal batteries at elevated temperature
Zeyuan Li,Aijun Li,Aijun Li,Hanrui Zhang,Ruoqian Lin,Tianwei Jin,Qian Cheng,Xianghui Xiao,Wah-Keat Lee,Mingyuan Ge,Haijun Zhang,Amirali Zangiabadi,Iradwikanari Waluyo,Adrian Hunt,Haowei Zhai,James Borovilas,Peiyu Wang,Xiao-Qing Yang,Xiuyun Chuan,Yuan Yang +19 more
TL;DR: In this article, the authors demonstrate a facile and effective strategy to enhance the interfacial stability by the synergy of Li1.5Al0.5Co 0.5(PO4)3 (LAGP) coating on the cathode surface, and salt combination in the electrolyte, even with a cut-off voltage of 4.25-4.4
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
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Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
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Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
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Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.